ANALYSIS OF NU-OH RAMAN-SPECTRA OF CDCL2-H2O-CH3OH SATURATED SOLUTIONS

被引:4
作者
STOEV, M [1 ]
ANACHKOVA, E [1 ]
ZLATEVA, I [1 ]
机构
[1] INST SOLID STATE PHYS,SOFIA,BULGARIA
关键词
D O I
10.1016/0167-7322(90)80022-C
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Raman spectra of ternary CdCl2H2OCH3OH solutions as well as of the corresponding H2OCH3OH solvents in the region of OH stretching mode have been mathematically analyzed. The best restoration of coincidence with the experimental spectra was obtained using four Gauss contours for electrolyte-water solutions and five in the case of methanol presence. Three set of parameters have been followed through the analysis: the stretching frequenciesω OH, the halfbandwidths Γ and the integrated intensities I of each contour normalized to the intensity of the whole ν OH spectrum. © 1990.
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页码:121 / 126
页数:6
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