POLYMERIZATION OF PHENYLACETYLENE CATALYZED BY A ZWITTERIONIC RHODIUM(I) COMPLEX UNDER HYDROSILYLATION CONDITIONS

被引：55

作者：

GOLDBERG, Y ^{[1
]}

ALPER, H ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA K1N 6N5,ON,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 10期

关键词：

D O I：

10.1039/c39940001209

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polymerisation of phenylacetylene occurs in the presence of triethylsilane and Rh+(cod)BPh(4)(-) to give stereoregular cis-poly(phenylacetylene) with ($) over bar M(w) of up to 35 000 (($) over bar M(w)/($) over bar M(n) = 1.7-5.0).

引用

页码：1209 / 1210

页数：2

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