COMPLEXES OF 2-FLUOROBENZOATE AND 4-FLUOROBENZOATE ANIONS AND THE CORRESPONDING METHYL-ESTERS WITH BETA-CYCLODEXTRIN AND THE CONJUGATE ACIDS OF 6(A)-AMINO-6(A)-DEOXY-BETA-CYCLODEXTRIN AND 3(A)-AMINO-3(A)-DEOXY-(2(A)S,3(A)S)-BETA-CYCLODEXTRIN IN AQUEOUS-SOLUTION - A F-19 NUCLEAR-MAGNETIC-RESONANCE STUDY

被引：0

作者：

EASTON, CJ ^{[1
]}

LINCOLN, SF ^{[1
]}

PAPAGEORGIOU, J ^{[1
]}

SCHLIEBS, DM ^{[1
]}

机构：

[1] UNIV ADELAIDE,DEPT CHEM,ADELAIDE,SA 5005,AUSTRALIA

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 1995年 / 10期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A F-19 NMR spectroscopic study shows that inclusion complexes of beta-cyclodextrin with aromatic guests are more stable than those of the conjugate acids of 6(A)-amino-6(A)-deoxy-beta-cyclodextrin and 3(A)-amino-3(A)-deoxy-(2(A)S,3(A)S)-beta-cyclodextrin, presumably as a result of the effect of the protonated amino substituents of the latter impinging on the character of their hydrophobic cavities.

引用

页码：381 / &

共 20 条

[1]

[Anonymous], 1961, BIOCH HDB

[2]

Bender M. L., 1977, CYCLODEXTRIN CHEM

[3] F-19 NUCLEAR MAGNETIC-RESONANCE STUDY OF THE INCLUSION OF FLUORO-TRANS-CINNAMATE AND DIFLUORO-TRANS-CINNAMATE BY ALPHA-CYCLODEXTRIN [J].

BRERETON, IM ;

SPOTSWOOD, TM ;

LINCOLN, SF ;

WILLIAMS, EH .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1984, 80 :3147-3156

[4] METALLOCYCLODEXTRINS OF 6(A)-(3-AMINOPROPYLAMINO)-6(A)-DEOXY-BETA-CYCLODEXTRIN - THEIR FORMATION AND ENANTIOSELECTIVE COMPLEXATION OF (R)-TRYPTOPHAN AND (S)-TRYPTOPHAN ANIONS IN AQUEOUS-SOLUTION [J].

BROWN, SE ;

COATES, JH ;

EASTON, CJ ;

LINCOLN, SF .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1994, 90 (05) :739-743

[5] TRYPTOPHAN ANION COMPLEXES OF BETA-CYCLODEXTRIN (CYCLOMALTAHEPTAOSE), AN AMINOPROPYLAMINO-BETA-CYCLODEXTRIN AND ITS ENANTIOSELECTIVE NICKEL(II) COMPLEX [J].

BROWN, SE ;

COATES, JH ;

EASTON, CJ ;

VANEYK, SJ ;

LINCOLN, SF ;

MAY, BL ;

STILE, MA ;

WHALLAND, CB ;

WILLIAMS, ML .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (01) :47-47

[6] SUBSTITUENT EFFECTS AND CHIRAL DISCRIMINATION IN THE COMPLEXATION OF BENZOIC, 4-METHYLBENZOIC AND (RS)-2-PHENYLPROPANOIC ACIDS AND THEIR CONJUGATE BASES BY BETA-CYCLODEXTRIN AND 6(A)-AMINO-6(A)-DEOXY-BETA-CYCLODEXTRIN IN AQUEOUS-SOLUTION - POTENTIOMETRIC TITRATION AND H-1 NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPIC STUDY [J].

BROWN, SE ;

COATES, JH ;

DUCKWORTH, PA ;

LINCOLN, SF ;

EASTON, CJ ;

MAY, BL .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (07) :1035-1040

[7]

BROWN SE, 1995, J CHEM RES-S, P2

[8] CHIRAL MOLECULAR RECOGNITION - A F-19 NUCLEAR-MAGNETIC-RESONANCE STUDY OF THE DIASTEREOISOMER INCLUSION COMPLEXES FORMED BETWEEN FLUORINATED AMINO-ACID DERIVATIVES AND ALPHA-CYCLODEXTRIN IN AQUEOUS-SOLUTION [J].

BROWN, SE ;

COATES, JH ;

LINCOLN, SF ;

COGHLAN, DR ;

EASTON, CJ .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (17) :2699-2703

[9] SYNTHESIS AND PROPERTIES OF 6A-AMINO-6A-DEOXY-ALPHA AND 6A-AMINO-6A-DEOXY-BETA-CYCLODEXTRIN [J].

BROWN, SE ;

COATES, JH ;

COGHLAN, DR ;

EASTON, CJ ;

VANEYK, SJ ;

JANOWSKI, W ;

LEPORE, A ;

LINCOLN, SF ;

LUO, Y ;

MAY, BL ;

SCHIESSER, DS ;

WANG, P ;

WILLIAMS, ML .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1993, 46 (06) :953-958

[10]

CLARKE RJ, 1989, ADV CARBOHYD CHEM BI, V46, P205

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