COPPER(I) AND GOLD(I) COMPLEXES WITH A PHOSPHORUS-SULFUR LIGAND - X-RAY STRUCTURE OF AUCL[(C6H5)(2)PCH2CH2SCH3]

被引：7
作者：
TURPIN, R
LARSONNEUR, AM
JAUD, J
CASTAN, P
机构：
[1] CHIM INORGAN LAB,TOULOUSE,FRANCE
[2] CEMES,LOE,CNRS,UPR 8011,TOULOUSE,FRANCE
来源：
INORGANICA CHIMICA ACTA | 1995年 / 237卷 / 1-2期
关键词：
CRYSTAL STRUCTURES; GOLD COMPLEXES; BIDENTATE PHOSPHINE COMPLEXES;
D O I：
10.1016/0020-1693(95)04679-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Complexes of Au(I) and Cu(I) with 1-(thiomethyl)-2-(diphenylphosphino) ethane (PSMe) have been prepared; the two products have the same general formula MCl(PSMe). The structure of the gold complex has been determined by X-ray crystallography. AuCl(PSMe) crystallizes in the monoclinic system, space group P2(1)/c, a = 11.618(9), b = 11.664(7), c = 13.013(8) Angstrom, V = 1615 Angstrom(3), beta = 113.6(1)degrees, Z = 4. The complex is linear with P-Au-Cl = 177.9(1)degrees. The copper complex has been studied by mass,IR and NMR spectroscopies, in view of the results so obtained we have postulated a dinuclear structure with a chloride bridge for this compound.
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页码：207 / 210
页数：4
相关论文
共 36 条
[11]   COORDINATION COMPLEXES OF ACETYLENE DIPHOSPHINES .I. DIPHOSPHINE-BRIDGED BINUCLEAR COPPER(I) AND GOLD(I) COMPLEXES OF BIS(DIPHENYLPHOSPHINO)ACETYLENE [J].
CARTY, AJ ;
EFRATY, A .
INORGANIC CHEMISTRY, 1969, 8 (03) :543-&
[12]   MOLECULES WITH AN M4X4 CORE .2. X-RAY CRYSTALLOGRAPHIC DETERMINATION OF MOLECULAR-STRUCTURE OF TETRAMERIC TRIPHENYLPHOSPHINECOPPER(I) BROMIDE IN CRYSTALLINE [PPH3CUBR]4.2CHCL3 [J].
CHURCHILL, MR ;
KALRA, KL .
INORGANIC CHEMISTRY, 1974, 13 (06) :1427-1434
[13]   MOLECULES WITH AN M4X4 CORE .1. CRYSTAL AND MOLECULAR-STRUCTURE OF TETRAMERIC TRIPHENYLPHOSPHINECOPPER(I) CHLORIDE, A CUBANE-LIKE MOLECULE, INCLUDING LOCATION AND REFINEMENT OF ALL HYDROGEN-ATOMS [J].
CHURCHILL, MR ;
KALRA, KL .
INORGANIC CHEMISTRY, 1974, 13 (05) :1065-1071
[14]   MOLECULES WITH AN M4X4 CORE .10. FAILURE OF THE 1-1-1 TRICYCLOHEXYLPHOSPHINE-COPPER(I)-CHLORIDE COMPLEX TO FORM A TETRAMER - CRYSTAL-STRUCTURE OF DIMERIC (TRICYCLOHEXYLPHOSPHINE)COPPER(I) CHLORIDE, [(P(CHX)3)CUCL]2 [J].
CHURCHILL, MR ;
ROTELLA, FJ .
INORGANIC CHEMISTRY, 1979, 18 (01) :166-171
[15]   TRIORGANOPHOSPHINEGOLD(I) COMPLEXES OF PYRIDINE-2-THIONATE AND PYRIMIDINE-2-THIONATE [J].
COOKSON, PD ;
TIEKINK, ERT .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (02) :259-263
[16]  
Cromer D.T, 1974, INT TABLES XRAY CRYS, VIV
[17]   SYNTHESES AND CHARACTERIZATION OF DINUCLEAR GOLD(I) RING AND OPEN-RING COMPLEXES CONTAINING SATURATED AND UNSATURATED DITHIOL BRIDGING LIGANDS AND PHOSPHINE OR BIS(DIPHOSPHINE) DONOR LIGANDS - CRYSTAL-STRUCTURES OF [AU2(MU-S(CH2)3S)(MU-DPPM)],[AU2(MU-MNT)(PPH3)2], [AU2(MU-S2C6H4)(PPH3)2], AND [AU4(MU-S2C6H3CH3)2(PET3)2] [J].
DAVILA, RM ;
ELDUQUE, A ;
GRANT, T ;
STAPLES, RJ ;
FACKLER, JP .
INORGANIC CHEMISTRY, 1993, 32 (09) :1749-1755
[18]   CARBONYL, HYDRIDOCARBONYL, AND HYDRIDOALKOXYCARBONYL COMPLEXES OF IRIDIUM WITH PHOSPHORUS-SULFUR HYBRID LIGANDS, AND THE CRYSTAL AND MOLECULAR-STRUCTURE OF [IRH(CO2ME)(PH2PCH2CH2SET)2]BPH4 [J].
DEL ZOTTO, A ;
MEZZETTI, A ;
DOLCETTI, G ;
RIGO, P .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (04) :607-613
[19]   REDUCTIVE CARBONYLATION OF COBALT(II) COMPLEXES WITH PHOSPHORUS SULFUR BIDENTATE LIGANDS [J].
DEL ZOTTO, A ;
RIGO, P .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 315 (02) :165-169
[20]   SYNTHESIS AND STRUCTURAL STUDIES OF RHODIUM COMPLEXES OF PHOSPHORUS SULFUR LIGANDS [J].
DICK, DG ;
STEPHAN, DW .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1986, 64 (09) :1870-1875
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