THERMAL-REACTIONS OF OXIRANES

被引：1

作者：

OYEWALE, AO ^{[1
]}

AITKEN, RA ^{[1
]}

机构：

[1] UNIV ST ANDREWS,DEPT CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

来源：

RUSSIAN CHEMICAL BULLETIN | 1995年 / 44卷 / 05期

关键词：

OXIRANES; PYROLYSIS; REARRANGEMENT; CLEAVAGE; BIRADICAL; DECOMPOSITION;

D O I：

10.1007/BF00696928

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The pyrolytic reactions of tetramethylethylene oxide, cyclopentene oxide, cyclohexene oxide, cyclooctene oxide, 1,2-epoxyethylbenzene, 1,2-epoxy-2-phenylpropane, 1,2-epoxy-1-phenylpropane, and 1,2-epoxy-1,2-diphenylethane were investigated at 600 degrees C using a conventional pyrolysis flow system. The products are mainly due to thermal cleavage of the oxirane ring followed by rearrangement to give carbonyl compounds.

引用

页码：919 / 922

页数：4

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