THE CHEMISTRY OF INDOLES .64. AN UNUSUAL 1-OXA-2-SILA-3-CYCLOPENTENE RING FORMATION IN THE PALLADIUM-CATALYZED REACTION OF THALLIUM COMPOUND WITH 2-METHYL-4-TRIMETHYLSILYL-3-BUTYN-2-OL

被引：3

作者：

OHTA, T ^{[1
]}

SHINODA, J ^{[1
]}

SOMEI, M ^{[1
]}

机构：

[1] KANAZAWA UNIV, FAC PHARMACEUT SCI, 13-1 TAKARA MACHI, KANAZAWA, ISHIKAWA 920, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 05期

关键词：

D O I：

10.1246/cl.1993.797

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A palladium catalyzed reaction of (3-formylindol-4-yl) thallium(III) bistrifluoroacetate with 2-methyl-4-trimethylsilyl-3-butyn-2-ol gave 4-(2,2,3,5,5-pentamethyl-1-oxa-2-sila-3-cyclopenten-4-yl)indole-3-carboxaldehyde.

引用

页码：797 / 798

页数：2

共 4 条

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[2] CLEAVAGE OF VINYL CARBON-SILICON BOND WITH TETRABUTYLAMMONIUM FLUORIDE
ODA, H
SATO, M
MORIZAWA, Y
OSHIMA, K
NOZAKI, H
[J]. TETRAHEDRON, 1985, 41 (16) : 3257 - 3268
[3] STUDIES DIRECTED TOWARD THE ULTIMATE SYNTHESIS FOR ERGOT ALKALOIDS
SOMEI, M
[J]. YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN, 1988, 108 (05): : 361 - 380
[4] SILAFUNCTIONAL COMPOUNDS IN ORGANIC-SYNTHESIS .31. STEREOCONTROL IN INTRAMOLECULAR HYDROSILATION OF ALLYL AND HOMOALLYL ALCOHOLS - A NEW APPROACH TO THE STEREOSELECTIVE SYNTHESIS OF 1,3-DIOL SKELETONS
TAMAO, K
NAKAJIMA, T
SUMIYA, R
ARAI, H
HIGUCHI, N
ITO, Y
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (19) : 6090 - 6093

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