STRUCTURE ELUCIDATION OF OXIDATION-REDUCTION PRODUCTS OF ISOLONGIFOLENE

被引：15

作者：

BOMBARDA, I

SMADJA, J

GAYDOU, EM

CONAN, JY

FAURE, R

机构：

[1] UNIV LA REUNION,CHIM ORGAN LAB,F-97490 ST DENIS,FRANCE

[2] FAC SCI & TECH ST JEROME,LAB PHYTOCHIM MARSEILLE,F-13397 MARSEILLE 20,FRANCE

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 1994年 / 42卷 / 01期

关键词：

D O I：

10.1021/jf00037a024

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

Three alcohol isomers have been synthesized in high yield from isolongifolene to provide easy-to-make and cheap odorants. Oxidation of isolongifolene by reaction with m-chloroperbenzoic acid yielded a mixture of the corresponding epoxide, ketone, and alcohol. Two other alcohols were obtained from the reduction of the epoxide and the ketone, respectively. An herbal, spicy, and earthy odor was detected from the ketone and alcohols. The structural formulas of the compounds were determined using one-and two-dimensional NMR and gas chromatography-mass spectrometry.

引用

页码：138 / 142

页数：5

共 34 条

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