TETRAKIS(IMIDAZOLE)COPPER(II) DIBROMIDE, [CU(HIM)(4)]BR-2

被引：11
作者：
PARKER, OJ
BRENEMAN, GL
机构：
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷
关键词：
D O I：
10.1107/S010827019401139X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structure of blue [Cu(C3H4N2)(4)]Br-2 consists of discrete [Cu(Him)(4)](2+) ions (Him = imidazole), with the Cu atom on an inversion center [Cu-N 1.997(4) and 2.008(3) Angstrom, N-Cu-N 89.9(1) and 90.1(1)degrees], and bromide ions [unique Cu ... Br- 3.3767(4) Angstrom] in the fifth and sixth octahedral sites above and below the CuN4 plane. The Br- ions also take part in a network of N-H ... Br- hydrogen bonds [N ... Br- 3.343(4) and 3.383(4) Angstrom].
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页码：1097 / 1099
页数：3
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