THE LIQUID-VAPOR COEXISTENCE OF CHARGED HARD-SPHERES

被引：4
|
作者：
CAILLOL, JM
机构：
[1] Lab. de Phys. Theor. et Hautes Energies, Univ. de Paris-Sud, Orsay
来源：
JOURNAL OF PHYSICS-CONDENSED MATTER | 1994年 / 6卷
关键词：
D O I：
10.1088/0953-8984/6/23A/024
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
We determine the liquid-vapour coexistence curve of the restricted primitive model of electrolytes by means of Monte Carlo simulations performed in the Gibbs ensemble and in a hyperspherical geometry. It is found that the Stillinger-Lovett condition is satisfied in the liquid phase but not in the vapour phase. This means that the latter could be dielectric. Whether this unexpected result is due to finite-size effects or not remains an open question.
引用
收藏
页码：A171 / A174
页数：4
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