EFFECT OF DODECANOL ON MIXED NONIONIC AND NONIONIC/ANIONIC SURFACTANT ADSORPTION AT THE AIR-WATER-INTERFACE

被引：38
|
作者：
STAPLES, EJ [1 ]
THOMPSON, L [1 ]
TUCKER, I [1 ]
PENFOLD, J [1 ]
机构：
[1] RUTHERFORD APPLETON LAB,ISIS SCI DIV,DIDCOT OX11 0QX,OXON,ENGLAND
来源：
LANGMUIR | 1994年 / 10卷 / 11期
关键词：
D O I：
10.1021/la00023a037
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Neutron reflection has been used to investigate the adsorption of mixed nonionic surfactant and nonionic/anionic surfactant mixtures containing dodecanol, at the air/water interface. The measurements clearly demonstrate the preferential adsorption of the more surface active shorter ethylene oxide nonionic surfactants, particularly of dodecanol. The usual trend for the more surface active components to decrease their presence in the surface layer as the total surfactant concentration increases is not observed for dodecanol. This results from the occurrence of unfavorable micellar geometries in mixtures containing dodecanol which control adsorption through their effect on monomer concentration. Regular solution theory cannot be used to describe the behavior of these systems.
引用
收藏
页码：4136 / 4141
页数：6
相关论文
共 50 条
  • [31] THE EFFECT OF MIXED CATIONIC-ANIONIC SURFACTANTS ON THE CLOUD POINT OF NONIONIC SURFACTANT
    HUANG, Z
    GU, TR
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1990, 138 (02) : 580 - 582
  • [32] THERMODYNAMICS OF ADSORPTION FOR ANIONIC-NONIONIC SURFACTANT MIXTURES ON ALUMINA
    FU, E
    SOMASUNDARAN, P
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 195 : 31 - PETR
  • [33] EFFECT OF SURFACTANT CONCENTRATION ON THE PROPERTIES OF ANIONIC NONIONIC MIXED-SURFACTANT OIL BRINE SYSTEMS
    ANDEREZ, JM
    BRACHO, CL
    SERENO, S
    SALAGER, JL
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1993, 76 : 249 - 256
  • [34] Anionic-nonionic and nonionic mixed surfactant systems for oil displacement: Impact of ethoxylate chain lengths on the synergistic effect
    Wang, Zizhao
    Dai, Caili
    Liu, Jiawei
    Dong, Yunbo
    Liu, Jinming
    Sun, Ning
    Li, Lin
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2023, 678
  • [35] SOLUTION PROPERTIES OF MIXED SURFACTANT SYSTEMS .4. THE EFFECT OF ALKYL CHAINS IN NONIONIC SURFACTANT ON ELECTRIC PROPERTIES OF ANIONIC-NONIONIC SURFACTANT SYSTEMS
    ABE, M
    TSUBAKI, N
    OGINO, K
    COLLOID AND POLYMER SCIENCE, 1984, 262 (07) : 584 - 588
  • [36] Adsorption behavior of cationic and nonionic surfactant mixtures at the alumina-water interface
    Huang, L
    Maltesh, C
    Somasundaran, P
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1996, 177 (01) : 222 - 228
  • [37] Interfacial and thermodynamic properties of anionic-nonionic mixed surfactant system: Influence of hydrophobic chain length of the nonionic surfactant
    Kadam, Mahesh M.
    Sawant, Manohar R.
    JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2006, 27 (06) : 861 - 868
  • [38] Temperature Resistant Binary SLES/Nonionic Surfactant Mixtures at the Air/Water Interface
    Smith, Charles
    Lu, Jian R.
    Tucker, Ian M.
    Grainger, David
    Li, Peixun
    Webster, John R. P.
    Thomas, Robert K.
    LANGMUIR, 2018, 34 (32) : 9442 - 9452
  • [39] THE COMPOSITION OF NONIONIC SURFACTANT MIXTURES AT THE AIR/WATER INTERFACE AS DETERMINED BY NEUTRON REFLECTIVITY
    PENFOLD, J
    STAPLES, E
    THOMPSON, L
    TUCKER, I
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1995, 102 : 127 - 132
  • [40] Competitive adsorption of nonionic surfactant and nonionic polymer on silica
    Postmus, Bart R.
    Leermakers, Frans A. M.
    Koopal, Luuk K.
    Stuart, Martien A. Cohen
    LANGMUIR, 2007, 23 (10) : 5532 - 5540
12345