MECHANISM OF OXIDATIVE COUPLING OF CONIFERYL ALCOHOL

被引：25
作者：
HAPIOT, P
PINSON, J
NETA, P
FRANCESCH, C
MHAMDI, F
ROLANDO, C
SCHNEIDER, S
机构：
[1] UNIV PARIS 07, ELECTROCHIM MOLEC LAB, F-75251 PARIS 05, FRANCE
[2] ECOLE NORMALE SUPER, DEPT CHIM, ACTIVAT MOLEC LAB, F-75231 PARIS 05, FRANCE
来源：
PHYTOCHEMISTRY | 1994年 / 36卷 / 04期
关键词：
CONIFERYL ALCOHOL; DIMERIZATION MECHANISM; CYCLIC VOLTAMMETRY; RADIOLYSIS;
D O I：
10.1016/S0031-9422(00)90482-5
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The dimerization mechanism of coniferyl alcohol in aqueous and non-aqueous media has been investigated by electrochemistry and by radiolysis. The coniferyl radical has been observed and shown to dimerize by a radical-radical coupling.
引用
收藏
页码：1013 / 1020
页数：8
相关论文
共 42 条
[1]   LIGNIN CHEMISTRY - PAST, PRESENT AND FUTURE [J].
ADLER, E .
WOOD SCIENCE AND TECHNOLOGY, 1977, 11 (03) :169-218
[2]   INTERMEDIATES IN THE OXIDATION OF AZIDE ION IN ACIDIC SOLUTIONS [J].
ALFASSI, ZB ;
PRUTZ, WA ;
SCHULER, RH .
JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (06) :1198-1203
[3]   REACTION OF AZIDE RADICALS WITH AROMATIC-COMPOUNDS - AZIDE AS A SELECTIVE OXIDANT [J].
ALFASSI, ZB ;
SCHULER, RH .
JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (15) :3359-3363
[4]   KINETIC-ANALYSIS OF REVERSIBLE ELECTRODIMERIZATION REACTIONS BY THE COMBINED USE OF DOUBLE POTENTIAL STEP CHRONOAMPEROMETRY AND LINEAR SWEEP VOLTAMMETRY - APPLICATION TO THE REDUCTION OF 9-CYANOANTHRACENE [J].
AMATORE, C ;
GARREAU, D ;
HAMMI, M ;
PINSON, J ;
SAVEANT, JM .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1985, 184 (01) :1-24
[5]   NANOSECOND TIME RESOLVED CYCLIC VOLTAMMETRY - DIRECT OBSERVATION OF ELECTROGENERATED INTERMEDIATES WITH BIMOLECULAR DIFFUSION CONTROLLED DECAY USING SCAN RATES IN THE MEGAVOLT PER 2ND RANGE [J].
AMATORE, CA ;
JUTAND, A ;
PFLUGER, F .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 218 (1-2) :361-365
[6]   FAST KINETICS BY MEANS OF DIRECT AND INDIRECT ELECTROCHEMICAL TECHNIQUES [J].
ANDRIEUX, CP ;
HAPIOT, P ;
SAVEANT, JM .
CHEMICAL REVIEWS, 1990, 90 (05) :723-738
[7]   FAST SWEEP CYCLIC VOLTAMMETRY AT ULTRA-MICROELECTRODES - EVALUATION OF THE METHOD FOR FAST ELECTRON-TRANSFER KINETIC MEASUREMENTS [J].
ANDRIEUX, CP ;
GARREAU, D ;
HAPIOT, P ;
PINSON, J ;
SAVEANT, JM .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 243 (02) :321-335
[8]   ULTRAMICROELECTRODES FOR FAST ELECTROCHEMICAL KINETICS [J].
ANDRIEUX, CP ;
HAPIOT, P ;
SAVEANT, JM .
ELECTROANALYSIS, 1990, 2 (03) :183-193
[9]  
ANDRIEUX CP, 1973, J ELECTROANAL CHEM, V42, P242
[10]  
ANDRIEUX CP, 1986, INVESTIGATION RATE 2, V6, pE41
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