SEPARATION OF CLOSE BOILING ALCOHOLS THROUGH SELECTIVE ETHERIFICATION WITH ISOBUTYLENE - USE OF ION-EXCHANGE RESINS AS CATALYST

被引：4

作者：

JAYADEOKAR, SS ^{[1
]}

SHARMA, MM ^{[1
]}

机构：

[1] UNIV BOMBAY,DEPT CHEM TECHNOL,BOMBAY 400019,INDIA

来源：

REACTIVE POLYMERS | 1993年 / 21卷 / 1-2期

关键词：

SEPARATION THROUGH REACTION; MIXED ALCOHOLS; TERT-BUTYL ETHERS; ION EXCHANGE RESIN CATALYSTS;

D O I：

10.1016/0923-1137(93)90052-H

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A novel way for the separation of mixtures of close boiling primary + secondary and secondary + tertiary alcohols through selective etherification with isobutylene in the presence of acidic ion exchange resins as catalysts is proposed. Mixtures of ethanol + isopropanol and isopropanol + tert-butanol were used as model components. The Langmuir-Hinshelwood model was used for studying the kinetics of these reactions.

引用

页码：37 / 43

页数：7