HOMOLOGATION OF TRIFLUOROACETIMIDOYL IODIDES BY PALLADIUM-CATALYZED CARBONYLATION - AN APPROACH TO ALPHA-AMINO PERFLUOROALKANOIC ACIDS

被引:50
作者
WATANABE, H [1 ]
HASHIZUME, Y [1 ]
UNEYAMA, K [1 ]
机构
[1] OKAYAMA UNIV,FAC ENGN,DEPT APPL CHEM,OKAYAMA 700,JAPAN
关键词
D O I
10.1016/S0040-4039(00)74253-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Homologation of trinuoroacetimidoyl iodides and the related perfluoro-compounds by palladium-catalyst under CO(1atm)-atmosphere in the presence of alcohols gives alpha-imino perfluoroatkanoates which are transformed to alpha-amino perfluoroalkanoic acids.
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页码:4333 / 4336
页数:4
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