RATES FOR THE REACTIONS OF OPEN-SHELL IONS WITH MOLECULES

被引：44

作者：

CLARY, DC ^{[1
]}

DATEO, CE ^{[1
]}

SMITH, D ^{[1
]}

机构：

[1] UNIV BIRMINGHAM,DEPT SPACE RES,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 167卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(90)85060-P

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Experimental rate coefficients for 34 exothermic reactions of C+ and N+ ions with molecules all take values between kc and fkc. Here, kc is a rate coefficient obtained from capture theory with a classical electrostatic potential and f is the fraction of potential energy surfaces that are attractive in the reactant channel. Ab initio calculations give f= 2 3 for C+ and f= 1 3 for N+. © 1990.

引用

页码：1 / 6

页数：6

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