SYNTHETIC AND STRUCTURAL STUDIES ON ORGANORUTHENIUM INDIUM COMPLEXES

被引：15
作者：
CALABRESE, JC
CLARKSON, LM
MARDER, TB
NORMAN, NC
TAYLOR, NJ
机构：
[1] DUPONT CO,DEPT CENT RES & DEV,EXPTL STN,POB 80228,WILMINGTON,DE 19880
[2] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND
[3] UNIV WATERLOO,DEPT CHEM,WATERLOO N2L 3G1,ONTARIO,CANADA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 24期
关键词：
D O I：
10.1039/dt9920003525
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and X-ray crystal structure of the triruthenium-indium complex [In{Ru(CO)2(eta-C5H5)}3] 1 are described. Complex 1 comprises a trigonal-planar indium centre bonded to three Ru(CO)2(eta-C5H5) fragments by unsupported In-Ru bonds. The magnitude of the In-Ru bond lengths are discussed with respect to pi bonding vs. ionic bonding in this and related compounds, and the possibility of pi bonding is also addressed with regard to the orientations of the Ru(CO)2(eta-C5H5) fragments in 1. The syntheses of the diruthenium complexes [InCl{Ru(CO)2(eta-C5H5)}2] and [N(PPh3)2]-[InCl2{Ru(CO)2(eta-C5H5)}2] are also described together with the X-ray crystal structure of the former.
引用
收藏
页码：3525 / 3529
页数：5
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