VINYLSTANNANES - SYNTHESIS AND CHARACTERIZATION

被引：15
作者：
JANATI, T
GUILLEMIN, JC
SOUFIAOUI, M
机构：
[1] UNIV RENNES 1,CNRS,URA 704,PHYSICOCHIM STRUCT GRP,F-35042 RENNES,FRANCE
[2] UNIV MOHAMMED 5,FAC SCI RABAT,RABAT,MOROCCO
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 486卷 / 1-2期
关键词：
VINYLSTANNANES; TIN; HYDRIDE; REDUCTION; NMR-STUDY;
D O I：
10.1016/0022-328X(94)05057-I
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Primary, secondary and tertiary vinylstannanes 2a-2f are synthesized by reduction of the corresponding chloro(vinyl)stannanes. They are characterized by their spectral data (IR, NMR (Sn-119, C-13, H-1) spectroscopy and mass spectrometry). The Sn-119 chemical shifts and (1)J(SnH) and (1)J(SnC) of vinylstannanes are compared with the data reported for the corresponding alkyl- and aryl-stannanes. Compounds 2 decompose slowly at room temperature in benzene (tau(1/2) 1-3 days). The formation of divinylchlorostannane and the use of trivinylstannane as a reducing agent are also reported.
引用
收藏
页码：57 / 62
页数：6
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