VINYLSTANNANES - SYNTHESIS AND CHARACTERIZATION

被引：15
|
作者：
JANATI, T
GUILLEMIN, JC
SOUFIAOUI, M
机构：
[1] UNIV RENNES 1,CNRS,URA 704,PHYSICOCHIM STRUCT GRP,F-35042 RENNES,FRANCE
[2] UNIV MOHAMMED 5,FAC SCI RABAT,RABAT,MOROCCO
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 486卷 / 1-2期
关键词：
VINYLSTANNANES; TIN; HYDRIDE; REDUCTION; NMR-STUDY;
D O I：
10.1016/0022-328X(94)05057-I
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Primary, secondary and tertiary vinylstannanes 2a-2f are synthesized by reduction of the corresponding chloro(vinyl)stannanes. They are characterized by their spectral data (IR, NMR (Sn-119, C-13, H-1) spectroscopy and mass spectrometry). The Sn-119 chemical shifts and (1)J(SnH) and (1)J(SnC) of vinylstannanes are compared with the data reported for the corresponding alkyl- and aryl-stannanes. Compounds 2 decompose slowly at room temperature in benzene (tau(1/2) 1-3 days). The formation of divinylchlorostannane and the use of trivinylstannane as a reducing agent are also reported.
引用
收藏
页码：57 / 62
页数：6
相关论文
共 50 条
  • [21] Synthesis and Characterization of Hexahydropyrimidines and Their New Derivatives
    Hamed, Shukkur A.
    Thaker, Athraa
    Rudaini, Bilal Majid
    Naeem, Hasanain Salah
    Abu Bakar, Muntaz
    Hasbullah, Siti Aishah
    SAINS MALAYSIANA, 2024, 53 (04): : 839 - 850
  • [22] Polyaniline/Graphite Nanocomposites: Synthesis and Characterization
    Gheno, Grasiela
    de Souza Basso, Nara Regina
    Huebler, Roberto
    BRAZILIAN POLYMER CONGRESS, 2011, 299-300 : 74 - 80
  • [23] Synthesis and characterization of potential impurities of ezetimibe
    Satheesh, Deekonda
    Devi, Dharmasoth Rama
    Basavaiah, Keloth
    Sreenivasulu, B.
    Reddy, Bhavanam Sekhara
    Aegurla, Balakrishna
    Kumar, Pallerla Satish
    Guduri, Anil Kumar
    Chavakula, Ramadas
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2023, 60 (02) : 318 - 326
  • [24] Refractory metal nanopowders: Synthesis and characterization
    Won, C. W.
    Nersisyan, H. H.
    Won, H. I.
    Lee, J. H.
    CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2010, 14 (3-4): : 53 - 68
  • [25] Synthesis, Characterization, and Applications of Copper Nanoparticles
    Din, Muhammad Imran
    Rehan, Rida
    ANALYTICAL LETTERS, 2017, 50 (01) : 50 - 62
  • [26] Synthesis and characterization of lithium oxonitrate (LiNO)
    Switzer, Christopher H.
    Miller, Thomas W.
    Farmer, Patrick J.
    Fukuto, Jon M.
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2013, 118 : 128 - 133
  • [27] Synthesis and characterization of chemically modified graphenes
    Park, Sungjin
    Ruoff, Rodney S.
    CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2015, 20 (5-6) : 322 - 328
  • [28] Synthesis and characterization of mesoporous carbon spheres
    Li, Shuiping
    Zhu, Huajun
    Xu, Guilong
    Lin, Qing
    Wang, Chengshuang
    Wu, Qisheng
    Wang, Zhanhong
    MATERIALS SCIENCE-POLAND, 2019, 37 (04) : 585 - 589
  • [29] Synthesis and characterization of a germanium bismethanediide complex
    Foo, Cechao
    Lau, Kai-Chung
    Yang, Yi-Fan
    So, Cheuk-Wai
    CHEMICAL COMMUNICATIONS, 2009, (44) : 6816 - 6818
  • [30] A Blueprint for the Synthesis and Characterization of Thiolated Graphene
    Rabchinskii, Maxim K.
    Sysoev, Victor V.
    Ryzhkov, Sergei A.
    Eliseyev, Ilya A.
    Stolyarova, Dina Yu.
    Antonov, Grigorii A.
    Struchkov, Nikolai S.
    Brzhezinskaya, Maria
    Kirilenko, Demid A.
    Pavlov, Sergei I.
    Palenov, Mihail E.
    Mishin, Maxim V.
    Kvashenkina, Olga E.
    Gabdullin, Pavel G.
    Varezhnikov, Alexey S.
    Solomatin, Maksim A.
    Brunkov, Pavel N.
    NANOMATERIALS, 2022, 12 (01)
12345