SPECTROSCOPIC INVESTIGATION OF FLUORESCENCE QUENCHING AGENTS .2. EFFECT OF NITROMETHANE ON THE FLUORESCENCE EMISSION BEHAVIOR OF 36 ALTERNANT BENZENOID POLYCYCLIC AROMATIC-HYDROCARBONS

被引：42
作者：
TUCKER, SA
DARMODJO, H
ACREE, WE
FETZER, JC
ZANDER, M
机构：
[1] UNIV N TEXAS,DEPT CHEM,DENTON,TX 76203
[2] CHEVRON RES & TECHNOL CTR,RICHMOND,CA 94802
[3] RUTGERSWERKE AG,W-4620 CASTROP RAUXEL,GERMANY
来源：
APPLIED SPECTROSCOPY | 1992年 / 46卷 / 08期
关键词：
D O I：
10.1366/0003702924123872
中图分类号：
TH7 [仪器、仪表];
学科分类号：
0804 ; 080401 ; 081102 ;
摘要：
Nitromethane is examined as a selective quenching agent for discriminating between "alternant" versus "nonalternant" polycyclic aromatic hydrocarbons in unknown mixtures. Of the 36 benzenoid solutes studied, only dibenzo[hi,wx]heptaphene failed to obey the selective quenching rule. Also reported are new experimental fluorescence probe studies for dibenzo[de,st]pentacene, dibenzo[fg,qr]pentacene, naphtho[8,1,2hij]-hexaphene, benzo[vwx]hexaphene, benzo[1,2,3cd;4,5,6c'd']diperylene, dibenzo[hi,wx]heptacene, benzo[b]triphenylene, chrysense, and anthracene dissolved in nonelectrolyte solvents of varying polarity. Benzo[vwx]hexaphene was found to exhibit probe character, as evidenced by a systematic variation in emission intensity ratio with solvent polarity.
引用
收藏
页码：1260 / 1265
页数：6
相关论文
共 58 条
[1]  
Acree W. E., 1991, POLYCYCL AROMAT COMP, V2, P75, DOI DOI 10.1080/10406639108048933
[2]   POLYCYCLIC AROMATIC HYDROCARBON SOLUTE PROBES .7. EVALUATION OF ADDITIONAL CORONENE DERIVATIVES AS POSSIBLE SOLVENT POLARITY PROBE MOLECULES [J].
ACREE, WE ;
TUCKER, SA ;
ZVAIGZNE, AI ;
STREET, KW ;
FETZER, JC ;
GRUTZMACHER, HF .
APPLIED SPECTROSCOPY, 1990, 44 (03) :477-482
[3]   POLYCYCLIC AROMATIC-HYDROCARBONS AND POLYCYCLIC AROMATIC SULFUR HETEROCYCLES - EXAMINATION OF MOLECULAR-STRUCTURE FLUORESCENCE PROBE CHARACTER CORRELATIONS [J].
ACREE, WE ;
TUCKER, SA ;
CRETELLA, LE ;
ZVAIGZNE, AI ;
STREET, KW ;
FETZER, JC ;
NAKASUJI, K ;
MURATA, I .
APPLIED SPECTROSCOPY, 1990, 44 (06) :951-957
[4]   SPECTROSCOPIC INVESTIGATION OF FLUORESCENCE QUENCHING AGENTS - EFFECT OF NITROMETHANE ON THE FLUORESCENCE EMISSION BEHAVIOR OF SELECT CYCLOPENTA-PAH, ACEANTHRYLENE, AND FLUORENE DERIVATIVES [J].
AMSZI, VL ;
CORDERO, Y ;
SMITH, B ;
TUCKER, SA ;
ACREE, WE ;
YANG, CX ;
ABUSHAQARA, E ;
HARVEY, RG .
APPLIED SPECTROSCOPY, 1992, 46 (07) :1156-1161
[5]   GROUP-SPECIFIC DETECTION OF POLYCYCLIC COMPOUNDS IN HIGH-PRESSURE LIQUID-CHROMATOGRAPHY BY SELECTIVE FLUORESCENCE QUENCHING [J].
BLUMER, GP ;
ZANDER, M .
FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1979, 296 (05) :409-410
[6]   FLUORESCENCE QUENCHING OF ALTERNANT AND NON-ALTERNANT POLYCYCLIC-HYDROCARBONS BY ELECTRON-TRANSFER [J].
BREYMANN, U ;
DREESKAMP, H ;
KOCH, E .
CHEMICAL PHYSICS LETTERS, 1978, 59 (01) :68-71
[7]  
BREYMANN U, 1978, Z ANAL CHEM, V293, P208
[8]   THE KALMAN FILTER IN ANALYTICAL-CHEMISTRY [J].
BROWN, SD .
ANALYTICA CHIMICA ACTA, 1986, 181 :1-29
[9]   CORRECTION FOR FLUORESCENCE RESPONSE SHIFTS IN POLYAROMATIC HYDROCARBON MIXTURES WITH AN INNOVATIONS-BASED KALMAN FILTER METHOD [J].
CECIL, TL ;
RUTAN, SC .
ANALYTICAL CHEMISTRY, 1990, 62 (18) :1998-2004
[10]   SELECTIVE FLUORESCENCE QUENCHING OF POLYNUCLEAR AROMATIC-HYDROCARBONS IN MICROCOLUMN LIQUID-CHROMATOGRAPHY [J].
CHEN, SH ;
EVANS, CE ;
MCGUFFIN, VL .
ANALYTICA CHIMICA ACTA, 1991, 246 (01) :65-74
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