INVESTIGATION OF THE CHARGE STATE OF HETEROATOMS IN ORGANIC-COMPOUNDS OF 3RD-ROW ELEMENTS BY X-RAY-FLUORESCENCE SPECTROSCOPY .11. REDISTRIBUTION OF ELECTRON-DENSITY IN SIMPLE PHOSPHORUS-CONTAINING MOLECULES UPON COMPLEXATION WITH ALBR3

被引：1
|
作者：
DOLENKO, GN
ELIN, VP
POLESHCHUK, OK
LITVIN, AL
VORONOV, VK
机构：
[1] Irkutsk Institute of Organic Chemistry, Academy of Sciences of the USSR, Siberian Branch
来源：
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1991年 / 40卷 / 02期
关键词：
D O I：
10.1007/BF00965430
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The electron density on the atom in the ligands PCl3, PPh3, SPCl3, and OPCl3 by means of which they are coordinated to a metal atom, decreases upon coordination with AlBr3 twice as much as does the total electron density of the ligands, and the ionicity of the PCl bonds in the ligands increases appreciably upon complexation.
引用
收藏
页码：352 / 354
页数：3
相关论文
共 8 条
1