EFFECT OF SPIN FLIP-FLOP ON ELECTRON-SPIN-ECHO DECAY DUE TO INSTANTANEOUS DIFFUSION

被引:19
作者
KURSHEV, VV [1 ]
ICHIKAWA, T [1 ]
机构
[1] HOKKAIDO UNIV,FAC ENGN,SAPPORO,HOKKAIDO 060,JAPAN
来源
JOURNAL OF MAGNETIC RESONANCE | 1992年 / 96卷 / 03期
关键词
D O I
10.1016/0022-2364(92)90341-4
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
The effect of electron spin flip-flop on two- and 2 + 1-pulse electron-spin-echo decay due to instantaneous diffusion was studied on hydrogen atoms in y-irradiated quartz. The observed decay was slower than the theoretical decay including no spin flip-flop, and the discrepancy increased with the concentration of the hydrogen atoms. A comparison of the theoretical and the experimental decay rates revealed that the main factor diminishing the effect of instantaneous diffusion is not the direct flip-flop between on-resonant spins, but the fluctuation of the local magnetic fields for on-resonant spins due to the flip-flop of adjacent spin pairs. © 1992.
引用
收藏
页码:563 / 573
页数:11
相关论文
共 12 条
[1]  
ABRAGAM A, 1961, PRINCIPLES NUCLEAR M
[2]  
CLAUDER JR, 1962, PHYS REV, V125, P912
[5]   SELECTION OF DIPOLAR INTERACTION BY THE 2+1 PULSE TRAIN ESE [J].
KURSHEV, VV ;
RAITSIMRING, AM ;
TSVETKOV, YD .
JOURNAL OF MAGNETIC RESONANCE, 1989, 81 (03) :441-454
[6]   SPATIAL-DISTRIBUTION OF FREE-RADICALS IN GAMMA-IRRADIATED ALCOHOL MATRICES DETERMINED BY THE 2+1 ELECTRON-SPIN ECHO METHOD [J].
KURSHEV, VV ;
RAITSIMRING, AM ;
ICHIKAWA, T .
JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (09) :3564-3568
[7]  
Mims WB., 1972, ELECTRON PARAMAGNETI, P263, DOI [DOI 10.1007/978-1-4899-5310-0_4, 10.1007/978-1-4899-5310-0_4]
[8]  
RAITSIMRING AM, 1975, FIZ TVERD TELA+, V17, P484
[9]  
Raitsimring AM., 1985, B MAGN RESON, V7, P184
[10]  
ROMANELLI M, 1991, J MAGN RESON, V91, P549, DOI 10.1016/0022-2364(91)90381-3