Synthesis, Characterization and Nonlinear Optical Property of the Barium Borate Halide Ba2B5O9Cl center dot 0.5H(2)O

被引：4

作者：

Zhang, Fangyuan ^{[1
,2
,3
]}

Zhang, Fangfang ^{[2
]}

Jia, Dianzeng ^{[1
]}

Pan, Shilie ^{[2
]}

机构：

[1] Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China

[2] Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

MATERIALS FOCUS | 2015年 / 4卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Barium Borate Halide; Second-Harmonic Generation; Non-Phase-Matching; Polarizability;

D O I：

10.1166/mat.2015.1206

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The hydrate barium borate halide Ba2B5O9Cl center dot 0.5H(2)O was synthesized under mild hydrothermal system BaCl2-H3BO3-H2O and its structure is determined by single-crystal X-ray diffraction method. The second harmonic generation (SHG) measurement indicates that Ba2B5O9Cl center dot 0.5H(2)O exhibits a type I, non-phase-matching response of approximately 1 x KH2PO4 (KDP). The effect of the structural units on the polarizability of the structure was discussed by dipole moment calculations based on the bond valence method. IR spectroscopy, UV-Vis-NIR diffuse reflectance spectroscopy and thermal properties of Ba2B5O9Cl center dot 0.5H(2)O were studied.

引用

页码：44 / 49

页数：6

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