PREPARATION AND PROPERTIES OF A NEW TEMPERATURE-SENSITIVE IONIZED GEL

被引:6
|
作者
KURAHASHI, H [1 ]
FURUSAKI, S [1 ]
机构
[1] UNIV TOKYO,DEPT CHEM ENGN,TOKYO 113,JAPAN
关键词
GEL; SPHERICAL MICROGEL; SWELLING; PHASE TRANSITION; VOLUME CHANGE; TEMPERATURE-SENSITIVE; PROTEIN; SEPARATION; DEXTRAN SULFATE; N-ISOPROPYLACRYLAMIDE;
D O I
10.1252/jcej.26.89
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A temperature-sensitive poly (N-isopropylacrylamide) (NIPA) gel containing dextran sulfate was synthesized. Dextran sulfate was entrapped in the crosslinked poly (NIPA). This hybrid gel showed a reversible volume change with temperature. The phase transition temperature of the hybrid gel was almost the same as that of the poly (NIPA) gel regardless of the fraction of dextran sulfate. The phase transition temperature of the ionized copolymer gel increased with the degree of gel ionization. The water-sorption capacity increased with dextran sulfate content. Exclusion and separation of proteins were found possible with hybrid gels of various dextran sulfate contents.
引用
收藏
页码:89 / 93
页数:5
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