ENTHALPIES OF SOLUTION OF TERT-BUTYL CHLORIDE AND BROMIDE IN BUTANOLS AND PENTANOLS

被引：4

作者：

GONCALVES, RMC

SIMOES, AMN

机构：

[1] Faculdade de Ciências de Lisboa, Lisboa, 1200, Calçada Bento da Rocha Cabral

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1990年 / 19卷 / 03期

关键词：

butanols; calorimetry; enthalpies of solution; pentanols; tert-Butyl chloride and bromide;

D O I：

10.1007/BF00650461

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The solution enthalpies at infinite dilution, ΔsH°, of the compounds t-BuCl and t-BuBr in 2-BuOH, i-BuOH, 2-PeOH and t-PeOH have been determined by solution calorimetry, between 25 and 40°C. The new results are discussed and compared with published values for other isomeric alcohols. © 1990 Plenum Publishing Corporation.

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页码：315 / 320

页数：6

相关论文

共 13 条

[1] DIELECTRIC CONSTANT OF HYDROGEN BONDED LIQUIDS .3. SUPERHEATED ALCOHOLS [J].

DANNHAUSER, W ;

BAHE, LW .

JOURNAL OF CHEMICAL PHYSICS, 1964, 40 (10) :3058-+

[2] STATIC DIELECTRIC-CONSTANT, VISCOSITY, AND STRUCTURE OF PURE ISOMERIC PENTANOLS [J].

DAPRANO, A ;

DONATO, DI ;

AGRIGENTO, V .

JOURNAL OF SOLUTION CHEMISTRY, 1981, 10 (09) :673-680

[3] HEATS OF SOLUTION OF GASEOUS HYDROCARBONS IN WATER AT 25-DEGREES-C [J].

DEC, SF ;

GILL, SJ .

JOURNAL OF SOLUTION CHEMISTRY, 1984, 13 (01) :27-41

[4] AN ELECTROSTATIC MODEL FOR HYDROGEN-BONDS IN ALCOHOLS [J].

GIGUERE, PA ;

PIGEONGOSSELIN, M .

JOURNAL OF SOLUTION CHEMISTRY, 1988, 17 (11) :1007-1014

[5] ENTHALPIES AND HEAT-CAPACITIES OF SOLUTION FOR TERT-BUTYL CHLORIDE AND BROMIDE IN ALCOHOLS - APPLICATION OF SPT, SRMR, AND MS [J].

GONCALVES, RMC ;

SIMOES, AMN .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1987, 65 (07) :1474-1478

[6] ENTHALPIES OF SOLUTION OF TERT-BUTYL CHLORIDE AND BROMIDE AND CARBON-TETRACHLORIDE AND TETRABROMIDE IN ALCOHOLS [J].

GONCALVES, RMC ;

SIMOES, AMN .

JOURNAL OF SOLUTION CHEMISTRY, 1987, 16 (01) :39-43

[7]

Hill JO., 1969, J CHEM THERMODYN, V1, P111, DOI [10.1016/0021-9614(69)90041-X, DOI 10.1016/0021-9614(69)90041-X]

[8] SCALED PARTICLE THEORY OF AQUEOUS AND NON-AQUEOUS SOLUTIONS [J].

PIEROTTI, RA .

CHEMICAL REVIEWS, 1976, 76 (06) :717-726

[9]

RAMOS JJM, 1977, J CHEM RES S, P56

[10]

RAMOS JJM, 1977, J CHEM RES M, P658