MICROWAVE SPECTRUM STRUCTURE AND DIPOLE MOMENT OF DIFLUOROPHOSPHINE OXIDE

被引：22

作者：

CENTOFANTI, LF

KUCZKOWS.RL

机构：

[1] Department of Chemistry, University of Michigan, Ann Arbor

来源：

INORGANIC CHEMISTRY | 1968年 / 7卷 / 12期

关键词：

D O I：

10.1021/ic50070a023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The microwave spectra of HF2PO, DF2PO, and HF2P18O have been analyzed. The structural parameters are d(PH) = 1.387 ± 0.01 Å, d(PF) = 1.539 ± 0.003 Å, d(PO) = 1.437 ± 0.006 Å, ZHPO = 117.9 ± 2°, ZFPO = 116.3 ± 1°, ZHPF = 101.9 ± 1. 5°, and ZFPF = 99.8±0.5°. The dipole moment was evaluated as 2.65 ± 0.03 D. © 1968, American Chemical Society. All rights reserved.

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页码：2582 / +

页数：1

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