ION-SENSITIVE FIELD-EFFECT TRANSISTORS WITH ULTRATHIN LANGMUIR-BLODGETT MEMBRANES

被引:11
|
作者
SCHONING, MJ [1 ]
SAUKE, M [1 ]
STEFFEN, A [1 ]
MARSO, M [1 ]
KORDOS, P [1 ]
LUTH, H [1 ]
KAUFFMANN, F [1 ]
ERBACH, R [1 ]
HOFFMANN, B [1 ]
机构
[1] UNIV KARLSRUHE, INST TECHNOL ELEKTROTECH, D-76187 KARLSRUHE, GERMANY
关键词
ISFETS; MEMBRANES; LANGMUIR-BLODGETT MEMBRANES;
D O I
10.1016/0925-4005(94)01611-K
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Novel ISFET devices coated with ultrathin Langmuir-Blodgett (LB) membranes are suitable for sodium detection in liquids. Successful deposition of a Na+-ion sensitive LB film onto structured ISFET surfaces has been achieved. The LB material consists of a rod-like LB polymer mixed with a commercially available sodium ionophore. A thin additional LB covering layer increases the sensor stability in contact with the electrolytes. The ISFET sensors show a nearly Nernstian sodium sensitivity of more than 52 mV/pNa in the range 10(-3) to 1 mol/l over a period of at least 30 days. A maximum response time after concentration changes of less than 1 min was determined. Selectivities were investigated to interfering ions like K+, Ca2+, Mg2+ and H+. The obtained results are in good agreement with the sensor properties of capacitive silicon/SiO2 structures coated with LB membranes of the same kind.
引用
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页码:325 / 328
页数:4
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