X-RAY STRUCTURE OF PT(DIPIC)(H2O) (WHERE H(2)DIPIC=2,6-PYRIDINEDICARBOXYLIC ACID) - THE FIRST STRUCTURALLY CHARACTERIZED MONONUCLEAR COMPLEX WITH A PT-II(N1O3) DONOR ATOM SET

被引：11

作者：

GOODGAME, DML

MULLER, TE

WILLIAMS, DJ

机构：

[1] Chemistry Department, Imperial College of Science, Technology and Medicine, London

来源：

POLYHEDRON | 1995年 / 14卷 / 17-18期

关键词：

D O I：

10.1016/0277-5387(95)00044-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of trans-[Pt(Hdipic)(2)]. 2H(2)O, where H(2)dipic = 2,6-pyridinedi-carboxylic acid, with thorium nitrate in water results in the abstraction of one of the dipic ligands and the formation of the compound Pt(dipic)(H2O). This has been shown by a single-crystal X-ray diffraction study to have the surprisingly rare mononuclear Pt-II (N1O3) coordination geometry. It appears to be the first structurally characterized example of a mononuclear Pt-II complex with that type of donor atom set.

引用

页码：2557 / 2559

页数：3

共 50 条

[31] Protonation of platinum(II) pyrazolates: Synthesis, characterization and X-ray crystal structure of [Pt(dppe)(Hpz-N)2][BF4]2·CHCl 3·H2O (Hpz-N=unsubstituted pyrazole)
Laura Bandini, Anna
Banditelli, Guido
Bovio, Bruna
1600, Elsevier Ltd (20): : 22 - 23
[32] Diaquabis(ethylenediamine)copper(II) vs. monoaquabis (ethylenediamine)copper(II): Synthesis, characterization, single crystal X-ray structure determination, theoretical calculations and antimicrobial activities of [Cu(en)2(H2O)2](2-phenoxybenzoate)2•H2O and [Cu(en)2(H2O)](diphenylacetate)2•3H2O
Sharma, Raj Pal
Saini, Anju
Kumar, Santosh
Kumar, Jitendra
Venugopalan, Paloth
Gondil, Vijay Singh
Chhibber, Sanjay
Aree, Thammarat
POLYHEDRON, 2017, 123 : 430 - 440
[33] Synthesis, characterisation and X-ray study of cobalt (II) complex: [Dimalonato tetraaqua cobalt (II)] [ Co(C4H3O4)2(H2O)4]
Abdelhak, Jawher
Cherni, Sawssen Namouchi
Zid, Mohamed Faouzi
Driss, Ahmed
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2007, 63 : S194 - S194
[34] X-RAY CRYSTAL-STRUCTURE AND ELECTRONIC-SPECTRUM OF THE COMPLEX [CO(C3H4N2)4(H2O)2](C6H4COSO2N)2
LI, JM
ZHANG, YG
LIN, WB
LIU, SX
HUANG, JL
POLYHEDRON, 1992, 11 (04) : 419 - 422
[35] A new binuclear germanium(IV) and copper(II) complex with 1,3-diamino-2-propanoltetraacetic acid: Crystal and molecular structure of [(H2O)(OH)Ge(μ-Hpdta)Cu(H2O)] • 3H2O
Martsinko, E. E.
Minacheva, L. Kh.
Sergienko, V. S.
Chebanenko, E. A.
Seifullina, I. I.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2010, 55 (12) : 1874 - 1881
[36] A new binuclear germanium(IV) and copper(II) complex with 1,3-diamino-2-propanoltetraacetic acid: Crystal and molecular structure of [(H2O)(OH)Ge(μ-Hpdta)Cu(H2O)] · 3H2O
E. E. Martsinko
L. Kh. Minacheva
V. S. Sergienko
E. A. Chebanenko
I. I. Seifullina
Russian Journal of Inorganic Chemistry, 2010, 55 : 1874 - 1881
[37] SYNTHESIS AND CHARACTERIZATION OF SOME METAL(II) COMPLEXES OF QUINOLINIC ACID (H-2-QUIN) AND X-RAY CRYSTAL-STRUCTURES OF [NI(H-QUIN)2(H2O)2] AND [MN(H2O)6][MN(H-QUIN)3]2
GOHER, MAS
YOUSSEF, AA
ZHOU, ZY
MAK, TCW
POLYHEDRON, 1993, 12 (15) : 1871 - 1878
[38] Catalytic auto-condensation of 2,4-pentanedione promoted by Sm(III) acetylacetonate:: the X-ray structure of a novel complex [Sm(CH3COO)3(H2O)2] (H2O)2
Arias, JL
Cabrera, A
Sharma, P
Rosas, N
García, JL
Hernandez, S
INORGANICA CHIMICA ACTA, 2000, 310 (02) : 261 - 264
[39] A self assembled 3-D network propagated by coordination polymerization and H-bonding: synthesis and X-ray crystal structure of [{Co(L)2(H2O)2}(ClO4)2(CH3COCH3)2(H2O)2]n, where L = N,N-diisopropylisonicotinamide
Pannu, Ajay Pal Singh
Kapoor, Pratibha
Hundal, Geeta
Kapoor, Ramesh
Martinez-Ripoll, Martin
Hundal, Maninder Singh
JOURNAL OF COORDINATION CHEMISTRY, 2011, 64 (09) : 1566 - 1577
[40] Manganese(II) salicylate complexes as H2O2 disproportionation catalysts: X-ray crystal structure of [Mn(Hsal)(2)(bipy)].H2O (H(2)sal equals salicylic acid, bipy=2,2'-bipyridine)
Devereux, M
Curran, M
McCann, M
Casey, MT
McKee, V
POLYHEDRON, 1996, 15 (12) : 2029 - 2033

← 1 2 3 4 5 →