HYDROSILATION OF DIENES CATALYZED BY CP-ASTERISK-2NDCH(SIME(3))(2)

被引：64

作者：

ONOZAWA, S

SAKAKURA, T

TANAKA, M

机构：

[1] NATL INST MAT & CHEM RES,TSUKUBA,IBARAKI 305,JAPAN

[2] UNIV TSUKUBA,DEPT CHEM,TSUKUBA,IBARAKI 305,JAPAN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 44期

关键词：

D O I：

10.1016/0040-4039(94)88276-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cp*2NdCH(SiMe(3))(2) efficiently catalyzes hydrosilation of 1,3-, 1,5-, and 1,6-dienes under mild conditions with unusual selectivities as compared with later transition metal-catalyzed reactions; hydrosilation of isoprene affords mainly (E)-, not (Z)-, allylsilane. On the other hand, hydrosilation of 1,5- and 1,6-dienes proceeds through intramolecular C-C bond formation to give (silylmethyl)cyclopentanes.

引用

收藏

页码：8177 / 8180

页数：4

相关论文

共 25 条

[11] HYDROSILYLATION OF OLEFINS WITH MONOSILANE CATALYZED BY TRANSITION-METAL COMPLEXES [J].

ITOH, M ;

IWATA, K ;

TAKEUCHI, R ;

KOBAYASHI, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 420 (02) :C5-C8

[12] DEHYDROGENATIVE SILYLATION OF 1,5-DIENES WITH HYDROSILANES CATALYZED BY RHCL(PPH3)3 [J].

KAKIUCHI, F ;

NOGAMI, K ;

CHATANI, N ;

SEKI, Y ;

MURAI, S .

ORGANOMETALLICS, 1993, 12 (12) :4748-4750

[13] GROUP-4 METALLOCENE OLEFIN HYDROSILYLATION CATALYSTS [J].

KESTI, MR ;

WAYMOUTH, RM .

ORGANOMETALLICS, 1992, 11 (03) :1095-1103

[14] HOMOLYTIC SUBSTITUTION-REACTION AT A SILICON ATOM [J].

KULICKE, KJ ;

CHATGILIALOGLU, C ;

KOPPING, B ;

GIESE, B .

HELVETICA CHIMICA ACTA, 1992, 75 (03) :935-939

[15] SELECTIVE HYDROSILYLATION OF ALKENES CATALYZED BY AN ORGANOYTTRIUM COMPLEX [J].

MOLANDER, GA ;

JULIUS, M .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (23) :6347-6351

[16] ORGANO-F-ELEMENT THERMOCHEMISTRY - ACTINIDE GROUP-14 ELEMENT AND ACTINIDE TRANSITION-ELEMENT BOND DISRUPTION ENTHALPIES AND STOICHIOMETRIC CATALYTIC CHEMICAL IMPLICATIONS THEREOF IN HETEROBIMETALLIC TRIS(CYCLOPENTADIENYL)URANIUM(IV) COMPOUNDS [J].

NOLAN, SP ;

PORCHIA, M ;

MARKS, TJ .

ORGANOMETALLICS, 1991, 10 (05) :1450-1457

[17] RH4(CO)12, CO2RH2(CO)12, AND CO3RH(CO)12 AS EFFECTIVE CATALYSTS FOR HYDROSILYLATION OF ISOPRENE, CYCLOHEXANONE, AND CYCLOHEXENONE [J].

OJIMA, I ;

DONOVAN, RJ ;

CLOS, N .

ORGANOMETALLICS, 1991, 10 (08) :2606-2610

[18] REGIOSELECTIVE HYDROSILYLATION OF 1,3-DIENES CATALYZED BY PHOSPHINE COMPLEXES OF PALLADIUM AND RHODIUM [J].

OJIMA, I ;

KUMAGAI, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 157 (03) :359-372

[19] SYNTHESIS AND CHARACTERIZATION OF THE NEUTRAL LANTHANIDE SILYL COMPLEXES (ETA-5-C5ME5)2LNSIH(SIME3)2 (LN = ND, SM) [J].

RADU, NS ;

TILLEY, TD ;

RHEINGOLD, AL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (21) :8293-8295

[20] HYDROSILYLATION CATALYZED BY ORGANONEODYMIUM COMPLEXES [J].

SAKAKURA, T ;

LAUTENSCHLAGER, HJ ;

TANAKA, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (01) :40-41