PALLADIUM-CATALYZED HYDROSTANNATION OF ALKOXYALLENES - A NEW ACCESS TO FUNCTIONALIZED ALLYLSTANNANES

被引：41

作者：

KOERBER, K

GORE, J

VATELE, JM

机构：

[1] Laboratoire de Chimie Organique 1, associé au CNRS, Université Claude Bernard, 69622 Villeurbanne, 43 Bd du

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 09期

关键词：

D O I：

10.1016/S0040-4039(00)92040-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of allenic ethers with HSnBu3 or HSnPh3, in the presence of Pd(PPh3)4, regioselectively gives allylstannanes in good yield. The stereoselectivity of the addition, which is a function of the substrate, is sensitive to reactions conditions.

引用

页码：1187 / 1190

页数：4

共 22 条

[11] PALLADIUM-CATALYZED ADDITION OF THE SILICON TIN BOND TO ALK-1-YNES AND 1,1-DIMETHYLALLENE [J].

MITCHELL, TN ;

KILLING, H ;

DICKE, R ;

WICKENKAMP, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (06) :354-355

[12] PALLADIUM(0) CATALYZED HYDROSTANNYLATION OF ALKYNES - STEREOSPECIFIC SYN ADDITION OF TRIBUTYLTIN HYDRIDE [J].

MIYAKE, H ;

YAMAMURA, K .

CHEMISTRY LETTERS, 1989, (06) :981-984

[13] HOMOGENEOUS SONOCHEMISTRY IN RADICAL CHAIN REACTIONS - SONOCHEMICAL HYDROSTANNATION AND TIN HYDRIDE REDUCTION [J].

NAKAMURA, E ;

MACHII, D ;

INUBUSHI, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (17) :6849-6850

[14] ET3B-INDUCED RADICAL-ADDITION OF R3SNH TO ACETYLENES AND ITS APPLICATION TO CYCLIZATION REACTION [J].

NOZAKI, K ;

OSHIMA, K ;

UTIMOTO, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (08) :2547-2549

[15] CLEAVAGE OF VINYL CARBON-SILICON BOND WITH TETRABUTYLAMMONIUM FLUORIDE [J].

ODA, H ;

SATO, M ;

MORIZAWA, Y ;

OSHIMA, K ;

NOZAKI, H .

TETRAHEDRON, 1985, 41 (16) :3257-3268

[16]

Pereyre M., 1987, TIN ORGANIC SYNTHESI

[17] TRISUBSTITUTED (STANNYLMETHYL)LITHIUM AS A METHYLENE DOUBLE ANION EQUIVALENT - REACTION WITH ESTERS [J].

SATO, T ;

MATSUOKA, H ;

IGARASHI, T ;

MINOMURA, M ;

MURAYAMA, E .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (06) :1207-1212

[18] SELECTIVE SYNTHESIS OF (Z)-ALK-2-ENENITRILES FROM ALDEHYDES [J].

SATO, Y ;

NIINOMI, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (01) :56-57

[19] A CATIONIC CYCLOPENTANNELATION [J].

TIUS, MA ;

ASTRAB, DP .

TETRAHEDRON LETTERS, 1984, 25 (15) :1539-1542

[20] GROUP-VIII METAL PHOSPHINE COMPLEXES-CATALYZED ADDITION OF DISILANES TO ALLENIC COMPOUNDS - FORMATION OF NEW ORGANO-SILICON COMPOUNDS CONTAINING BOTH VINYLSILANE AND ALLYLSILANE UNITS [J].

WATANABE, H ;

SAITO, M ;

SUTOU, N ;

KISHIMOTO, K ;

INOSE, J ;

NAGAI, Y .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 225 (01) :343-356

← 1 2 3 →