REACTION OF ME2SBR2 AND PRN3PL2 WITH TIN METAL-POWDER - A NOVEL ROUTE TO METAL THIOETHER COMPLEXES AND THE 1ST TIN(IV) PHOSPHINE COMPLEX CONTAINING IODIDE LIGANDS

被引：29

作者：

BRICKLEBANK, N ^{[1
]}

GODFREY, SM ^{[1
]}

MCAULIFFE, CA ^{[1
]}

PRITCHARD, RG ^{[1
]}

机构：

[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 06期

关键词：

D O I：

10.1039/c39940000695

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tin metal powder reacts readily with both Me2SBr2 and Prn3PI2 in diethyl ether under ambient conditions, producing the novel SnBr4(SMe2)2, which contains both cis and trans isomers within the unit cell, and the first complex of stoichiometry SnI4(PR3)2 to be isolated: both complexes have been crystallographically characterised.

引用

页码：695 / 696

页数：2

共 31 条

[1] STRUCTURE OF A HALOSULFONIUM SALT - 1-1 ADDUCT OF THIOPHANE WITH BROMINE [J].

ALLEGRA, G ;

WILSON, GE ;

BENEDETT.E ;

PEDONE, C ;

ALBERT, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (13) :4002-&

[2] THE CONSTITUTION OF COMPLEX METALLIC SALTS .14. THE ACTION OF TRIALKYL-PHOSPHINES AND TRIALKYL-ARSINES ON THE TETRAHALIDES OF TIN AND URANIUM [J].

ALLISON, JAC ;

MANN, FG .

JOURNAL OF THE CHEMICAL SOCIETY, 1949, (NOV) :2915-2921

[3] RAMAN-SPECTRA OF SOME COMPLEXES CONTAINING METHYLDIHALO-SULFONIUM AND DIMETHYLHALO-SULFONIUM CATIONS - ISOMERISM IN THE DIMETHYL SULFIDE BROMINE COMPLEX [J].

ASKEW, HF ;

GATES, PN ;

MUIR, AS .

JOURNAL OF RAMAN SPECTROSCOPY, 1991, 22 (05) :265-274

[4] STRUCTURE OF TRANS-TETRACHLOROBIS(TETRAHYDROTHIOPHEN)TIN(4) IN SOLID STATE AND IN SOLUTION [J].

BEATTIE, IR ;

HULME, R ;

RULE, L .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (MAR) :1581-&

[5] THE ACCEPTOR PROPERTIES OF QUADRIPOSITIVE SILICON, GERMANIUM, TIN, AND LEAD [J].

BEATTIE, IR .

QUARTERLY REVIEWS, 1963, 17 (04) :382-405

[6] DIIODOPHOSPHORANES - SYNTHESIS AND STRUCTURE IN THE SOLID-STATE AND IN SOLUTION [J].

BRICKLEBANK, N ;

GODFREY, SM ;

MACKIE, AG ;

MCAULIFFE, CA ;

PRITCHARD, RG ;

KOBRYN, PJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (01) :101-103

[7] THE X-RAY CRYSTAL-STRUCTURE OF [ZN(PET3)I2]2, THE 1ST 1/1 ZINC(II) COMPLEX OF A TERTIARY PHOSPHINE OF LOW STERIC REQUIREMENTS, PREPARED BY THE REACTION OF UNACTIVATED ZINC METAL WITH DIIODOTRIETHYLPHOSPHORANE [J].

BRICKLEBANK, N ;

GODFREY, SM ;

MCAULIFFE, CA ;

MACKIE, AG ;

PRITCHARD, RG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (13) :944-945

[8] THE STRUCTURE OF TRIPHENYLPHOSPHORUS DIBROMINE, THE 1ST-CRYSTALLOGRAPHICALLY CHARACTERIZED BROMOPHOSPHORANE, A COMPOUND WHICH HAS THE NOVEL 4-COORDINATE MOLECULAR PH3P-BR-BR GEOMETRY [J].

BRICKLEBANK, N ;

GODFREY, SM ;

MACKIE, AG ;

MCAULIFFE, CA ;

PRITCHARD, RG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (04) :355-356

[9]

BRICKLEBANK N, 1993, J CHEM SOC DA, P2061

[10] A STUDY OF CIS-OCTAHEDRAL COMPOUNDS OF TIN(IV) HALIDES WITH THIOUREA OR UREA TYPE LIGANDS [J].

CALOGERO, S ;

RUSSO, U ;

VALLE, G ;

BARNARD, PWC ;

DONALDSON, JD .

INORGANICA CHIMICA ACTA-ARTICLES, 1982, 59 (01) :111-116

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