NMR COUPLING OF C-13 AND F-19 WITH N-14 IN NITRO-COMPOUNDS

被引：16

作者：

COBURN, MD

STORM, CB

MOORE, DW

ARCHIBALD, TG

机构：

[1] USN,CTR WEAP,CHINA LAKE,CA 93555

[2] FLUOROCHEM INC,AZUSA,CA 91702

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1990年 / 28卷 / 01期

关键词：

!sup]13[!/sup]C NMR; !sup]14[!/sup]N NMR; !sup]19[!/sup]F NMR; Nitro compounds;

D O I：

10.1002/mrc.1260280105

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 13C and 14N NMR spectra of a variety of highly nitrated aliphatic, aromatic and heterocyclic compounds were obtained. The proton decoupled 13C peaks of the nitro‐substituted carbons in most of these compounds were split into the multiplets expected for coupling with spin 1 nuclei with negligible quadrupolar broadening. In addition, the 19F spectra of some fluoronitroaliphatic compounds showed that the 19F signals were also split into the expected multiplets from coupling with the 14N of the nitro groups. Copyright © 1990 John Wiley & Sons, Ltd.

引用

页码：16 / 20

页数：5

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