ENHANCEMENT OF CATALYTIC ACTIVITY FOR HYDROFORMYLATION OF METHYL ACRYLATE BY USING BIPHASIC AND SUPPORTED AQUEOUS-PHASE SYSTEMS

被引：55
作者：
FREMY, G
MONFLIER, E
CARPENTER, JF
CASTANET, Y
MORTREUX, A
机构：
[1] UNIV SCI & TECHNOL LILLE,CATALYSE HETEROGENE & HOMOGENE LAB,F-59652 VILLENEUVE DASCQ,FRANCE
[2] UNIV ARTOIS,FAC SCI JEAN PERRIN,LENS,FRANCE
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 13-14期
关键词：
BIPHASIC CATALYSIS; CATALYSIS; HYDROFORMYLATION; METHYL ACRYLATE; RHODIUM CATALYSTS;
D O I：
10.1002/anie.199514741
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
High activities and selectivities are obtained for the rhodium‐catalyzed hydroformylation of methyl acrylate in biphasic and “supported aqueous phase” (SAP) systems [Eq. (a)]. The biphasic system Rh/P(C6H4SO3Na)3 1 is twice as active as the classic Rh/PPh3 combination (homogeneous system), and the SAP system Rh/P(C6H4SO3Na)3/SiO2 2 is twenty times more active. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
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页码：1474 / 1476
页数：3
相关论文
共 23 条
[1]   EXCELLENT REGIOCHEMICAL CONTROL IN THE HYDROFORMYLATION OF ALPHA,BETA-UNSATURATED ESTERS CATALYZED BY ZWITTERIONIC RHODIUM COMPLEXES AND 1,4-BIS(DIPHENYLPHOSPHINO)BUTANE [J].
ALPER, H ;
ZHOU, JQ .
JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (13) :3729-3731
[2]   HYDROFORMYLATION BY SUPPORTED AQUEOUS-PHASE CATALYSIS - A NEW CLASS OF HETEROGENEOUS CATALYSTS [J].
ARHANCET, JP ;
DAVIS, ME ;
MEROLA, JS ;
HANSON, BE .
NATURE, 1989, 339 (6224) :454-455
[3]   SUPPORTED AQUEOUS-PHASE, RHODIUM HYDROFORMYLATION CATALYSTS .2. HYDROFORMYLATION OF LINEAR, TERMINAL AND INTERNAL OLEFINS [J].
ARHANCET, JP ;
DAVIS, ME ;
HANSON, BE .
JOURNAL OF CATALYSIS, 1991, 129 (01) :100-105
[4]   SUPPORTED AQUEOUS-PHASE, RHODIUM HYDROFORMYLATION CATALYSTS .1. NEW METHODS OF PREPARATION [J].
ARHANCET, JP ;
DAVIS, ME ;
HANSON, BE .
JOURNAL OF CATALYSIS, 1991, 129 (01) :94-99
[5]  
Breed Antonius, 1989, Eur. Pat. Appl, Patent No. [EP 306094A2, 19890308, 306094]
[6]   P-31 NMR SPIN-LATTICE RELAXATION-TIMES AS AN INDIRECT PROBE OF ADSORBED WATER IN SUPPORTED AQUEOUS-PHASE CATALYSTS [J].
BUNN, BB ;
BARTIK, T ;
BARTIK, B ;
BEBOUT, WR ;
GLASS, TE ;
HANSON, BE .
JOURNAL OF MOLECULAR CATALYSIS, 1994, 94 (02) :157-161
[7]   ENHANCEMENT OF INTERFACIAL CATALYSIS IN A BIPHASIC SYSTEM USING CATALYST-BINDING LIGANDS [J].
CHAUDHARI, RV ;
BHANAGE, BM ;
DESHPANDE, RM ;
DELMAS, H .
NATURE, 1995, 373 (6514) :501-503
[8]  
DAVIS ME, 1992, CHEMTECH, P498
[9]   2-PHASE HYDROFORMYLATION OF OCTENE-1 WITH RHODIUM COMPLEXES OF P[C6H4(CH2)MC6H4-P-SO3NA]3 (M=3, 6) - RATE AND SELECTIVITY ENHANCEMENT WITH SURFACE-ACTIVE PHOSPHINES [J].
DING, H ;
HANSON, BE ;
BARTIK, T ;
BARTIK, B .
ORGANOMETALLICS, 1994, 13 (10) :3761-3763
[10]   RHODIUM-CATALYZED 2-PHASE HYDROFORMYLATION OF HEX-1-ENE WITH SULFONATED TRIS(4-FLUOROPHENYL)PHOSPHINE AS WATER-SOLUBLE COMPLEX LIGANDS [J].
FELL, B ;
PAPADOGIANAKIS, G .
JOURNAL FUR PRAKTISCHE CHEMIE-CHEMIKER-ZEITUNG, 1994, 336 (07) :591-595
123