SYNTHESIS AND CHARACTERIZATION OF CATIONIC BIS-AZIRIDINE COBALT(III) COMPLEXES CONTAINING SCHIFF-BASE LIGANDS

被引：32

作者：

WARE, DC ^{[1
]}

MACKIE, DS ^{[1
]}

BROTHERS, PJ ^{[1
]}

DENNY, WA ^{[1
]}

机构：

[1] UNIV AUCKLAND,SCH CHEM,CANC RES LAB,AUCKLAND,NEW ZEALAND

来源：

POLYHEDRON | 1995年 / 14卷 / 12期

关键词：

D O I：

10.1016/0277-5387(94)00427-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses of cationic bis-aziridine (Az) complexes, [Co(SB)(Az)(2)]Cl, where SB is a Schiff base ligand (SB = acacen, salen, salpn, hapen, happn or saloph) by oxidation of cobalt(II) in basic solution containing the ligands are described. A corresponding series of methylamine complexes [Co(SB)(CH3NH2)(2)]Cl was also prepared (SB = acacen, salen, salpn, hapen or saloph). Both series of complexes were characterized by H-1 NMR spectroscopy, while the aziridine complexes and selected methylamine complexes were also investigated by C-13 NMR spectroscopy.

引用

页码：1641 / 1646

页数：6

共 17 条

[11] N-ARYL SALICYLALDIMINE COMPLEXES - INFRARED AND PMR SPECTRA OF LIGANDS AND VIBRATIONAL FREQUENCIES OF THEIR METAL (II) CHELATES
PERCY, GC
THORNTON, DA
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1972, 34 (11): : 3357 - &
[12] ETHYLENIMINE BY FLASH DISTILLATION
REEVES, WA
DRAKE, GL
HOFFPAUIR, CL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (07) : 3522 - 3522
[13] HYPOXIA-SELECTIVE ANTITUMOR AGENTS .7. METAL-COMPLEXES OF ALIPHATIC MUSTARDS AS A NEW CLASS OF HYPOXIA-SELECTIVE CYTOTOXINS - SYNTHESIS AND EVALUATION OF COBALT(III) COMPLEXES OF BIDENTATE MUSTARDS
WARE, DC
PALMER, BD
WILSON, WR
DENNY, WA
[J]. JOURNAL OF MEDICINAL CHEMISTRY, 1993, 36 (13) : 1839 - 1846
[14] DESIGN AND SYNTHESIS OF COBALT(III) NITROGEN-MUSTARD COMPLEXES AS HYPOXIA SELECTIVE CYTOTOXINS - THE X-RAY CRYSTAL-STRUCTURE OF BIS(3-CHLOROPENTANE-2,4-DIONATO)(RS-N,N'-BIS(2-CHLOROETHYL)ETHYLENEDIAMINE)COBALT(III) PERCHLORATE, [CO(CLACAC)2(BCE)]CLO4
WARE, DC
WILSON, WR
DENNY, WA
RICKARD, CEF
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (17) : 1171 - 1173
[15] SYNTHESIS AND CHARACTERIZATION OF AZIRIDINE COMPLEXES OF COBALT(III) AND CHROMIUM(III) DESIGNED AS HYPOXIA-SELECTIVE CYTOTOXINS - X-RAY CRYSTAL-STRUCTURE OF TRANS-[CO(AZ)4(NO2)2]BR.2H2O.LIBR
WARE, DC
SIIM, BG
ROBINSON, KG
DENNY, WA
BROTHERS, PJ
CLARK, GR
[J]. INORGANIC CHEMISTRY, 1991, 30 (19) : 3750 - 3757
[16] SYNTHESIS AND CHARACTERIZATION OF MONO-ARIZIDINE AND BIS-AZIRIDINE BIS-DIMETHYLGLYOXIMATO COBALT(III) COMPLEXES
WARE, DC
MACKIE, DS
BROTHERS, PJ
DENNY, WA
[J]. POLYHEDRON, 1993, 12 (11) : 1371 - 1376
[17] COBALT(III) COMPLEXES WITH [N6-NXN]-TYPE LIGANDS .5. THE PREPARATION AND PROPERTIES OF N,N'-DISALICYLIDENE-SUBSTITUTED QUADRIDENTATE AMINE COBALT(III) COMPLEXES
YAMAMOTO, Y
TSUKUDA, S
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (05) : 1509 - 1515

← 1 2 →