SYNTHESIS AND CHARACTERIZATION OF CATIONIC BIS-AZIRIDINE COBALT(III) COMPLEXES CONTAINING SCHIFF-BASE LIGANDS

被引：32

作者：

WARE, DC ^{[1
]}

MACKIE, DS ^{[1
]}

BROTHERS, PJ ^{[1
]}

DENNY, WA ^{[1
]}

机构：

[1] UNIV AUCKLAND,SCH CHEM,CANC RES LAB,AUCKLAND,NEW ZEALAND

来源：

POLYHEDRON | 1995年 / 14卷 / 12期

关键词：

D O I：

10.1016/0277-5387(94)00427-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses of cationic bis-aziridine (Az) complexes, [Co(SB)(Az)(2)]Cl, where SB is a Schiff base ligand (SB = acacen, salen, salpn, hapen, happn or saloph) by oxidation of cobalt(II) in basic solution containing the ligands are described. A corresponding series of methylamine complexes [Co(SB)(CH3NH2)(2)]Cl was also prepared (SB = acacen, salen, salpn, hapen or saloph). Both series of complexes were characterized by H-1 NMR spectroscopy, while the aziridine complexes and selected methylamine complexes were also investigated by C-13 NMR spectroscopy.

引用

页码：1641 / 1646

页数：6

共 17 条

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