ACCELERATED FORMATION OF 110-K HIGH-TC PHASE IN THE CA-RICH AND CU-RICH BI-PB-SR-CA-CU-O SYSTEM

被引:42
作者
HUANG, YT [1 ]
LIU, RG [1 ]
LU, SW [1 ]
WU, PT [1 ]
WANG, WN [1 ]
机构
[1] CHUNG SHAN INST SCI & TECHNOL,TAOYUAN 32526,TAIWAN
关键词
D O I
10.1063/1.103315
中图分类号
O59 [应用物理学];
学科分类号
摘要
The crystal structure and superconducting properties of the Bi-Pb-Sr-Ca-Cu-O system with Ca- and Cu-rich nominal composition were investigated. A nearly single-phased 110 K high Tc superconductor can be obtained with 852 °C/20 h sintering from the starting composition of Bi1.7Pb0.4Sr1.6Ca2.4Cu 3.6Oy. X-ray diffraction patterns, resistivity measurement, diamagnetic susceptibility results, and scanning electron micrographs all indicate that the Ca- and Cu-rich nominal composition would result in better superconducting properties than those of Ca:Sr=1:1 Bi-Pb-Sr-Ca-Cu-O compounds in a much shorter sintering time.
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页码:779 / 781
页数:3
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