Pheromone synthesis .170. A new synthesis of faranal [(3S,4R,6E,10Z)-3,4,7,11-tetramethyl-6,10-tridecadienal], the trail pheromone of the Pharaoh's ant, Monomorium pharaonis

被引：0

作者：

Mori, K ^{[1
]}

Murata, N ^{[1
]}

机构：

[1] UNIV TOKYO,DEPT AGR CHEM,BUNKYO KU,TOKYO 113,JAPAN

来源：

LIEBIGS ANNALEN | 1995年 / 12期

关键词：

carboalumination; faranal; Monomorium pharaonis; Pharaoh's ant; pheromone; zirconocene dichloride;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Faranal (1), the trail-following pheromone of the worker of Pharaoh's ant (Monomorium pharaonis), was synthesized by the coupling reaction of the iododiene 3 with the chiral building block 8 as the key step. The geometrically pure iododiene 3 was prepared by the zirconocene-mediated carboalumination reaction of 2 followed by treatment with iodine.

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页码：2089 / 2092

页数：4

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