PHOTOOXIDATION OF 2-(2-FURYL)-1,3-DICARBONYL COMPOUNDS

被引:2
|
作者
ANTONIOLETTI, R [1 ]
BONADIES, F [1 ]
PESCI, S [1 ]
SCETTRI, A [1 ]
机构
[1] UNIV ROME LA SAPIENZA,CNR,DIPARTIMENTO CHIM,P A MORO 5,I-00185 ROME,ITALY
关键词
D O I
10.1016/S0040-4039(00)74826-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A very efficient photo-sensitized oxidation of 2-(2-furyl)-1,3-dicarbonyl compounds 1 afford directly hydroperoxides 2 in stereoselective way. Compounds 2, easily isolated, can be conveniently employed in a selective epoxidation of trisubstituted allylic alcohols by a Sharpless-type procedure.
引用
收藏
页码:3947 / 3948
页数:2
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