STEROL COMPOSITION AND BIOSYNTHESIS IN THE BLACK-SEA SPONGE DYSIDEA-FRAGILIS

被引：18
作者：
ELENKOV, I
MILKOVA, T
ANDREEV, S
POPOV, S
机构：
[1] BULGARIAN ACAD SCI,CTR PHYTOCHEM,INST ORGAN CHEM,BU-1113 SOFIA,BULGARIA
[2] BULGARIAN ACAD SCI,MUSEUM NAT HIST,BU-1000 SOFIA,BULGARIA
来源：
COMPARATIVE BIOCHEMISTRY AND PHYSIOLOGY B-BIOCHEMISTRY & MOLECULAR BIOLOGY | 1994年 / 107卷 / 04期
关键词：
STEROL COMPOSITION; DYSIDEA FRAGILIS;
D O I：
10.1016/0305-0491(94)90183-X
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The sterol composition of Dysidea fragilis from the Black Sea is reported. Three groups of sterols, Delta(5), Delta(0) and Delta(5,7), were found. The isolated 5 alpha,8 alpha- epidioxy sterols appeared to be predominantly, if not exclusively, artifacts. The auto-oxidation of native Delta(5,7)- sterols to 5 alpha,8 alpha- epidioxy sterols has been investigated. A transformation of dietary Delta(5)- sterols to Delta(5,7)- sterols has been demonstrated in Dysidea fragilis.
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收藏
页码：547 / 551
页数：5
相关论文
共 13 条
[1]   MINOR AND TRACE STEROLS IN MARINE-INVERTEBRATES .11. 5 ALPHA-24-NORCHOLESTAN-3 BETA-OL AND (24Z)-STIGMASTA-5,7,24 (28)-TRIEN-3 BETA-OL, 2 NEW MARINE STEROLS FROM THE PACIFIC SPONGES TERPIOS-ZETEKI AND DYSIDEA-HERBACEA [J].
DELSETH, C ;
TOLELA, L ;
SCHEUER, PJ ;
WELLS, RJ ;
DJERASSI, C .
HELVETICA CHIMICA ACTA, 1979, 62 (01) :101-109
[2]   METABOLISM IN PORIFERA .2. DISTRIBUTION OF STEROLS [J].
DEROSA, M ;
MINALE, L ;
SODANO, G .
COMPARATIVE BIOCHEMISTRY AND PHYSIOLOGY, 1973, 46 (4B) :823-837
[3]  
Dogovic N.P., 1979, B SOC CHIM BEOGRAD, V44, P321
[4]   BIOSYNTHETIC-STUDIES OF MARINE LIPIDS .20. SEQUENCE OF DOUBLE-BOND INTRODUCTION IN THE SPONGE STEROL 24-BETA-METHYLCHOLESTA-5,7,22,25-TETRAEN-3-BETA-OL [J].
JOHN, V ;
STOILOV, IL ;
DJERASSI, C ;
KARUSO, P ;
POINER, A ;
SCHEUER, PJ .
JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (07) :1642-1647
[5]  
MILKOVA T, 1985, 3RD INT C CHEM BIOTE, V5, P104
[6]   2 NEW POLYHYDROXYLATED STEROLS FROM THE SPONGE DYSIDEA-FRAGILIS [J].
MILKOVA, TS ;
MIKHOVA, BP ;
NIKOLOV, NM ;
POPOV, SS ;
ANDREEV, SN .
JOURNAL OF NATURAL PRODUCTS, 1992, 55 (07) :974-978
[7]   CHEMICAL IONIZATION MASS-SPECTROMETRY WITH AMINES AS REACTANT GASES .8. AMINE CHEMICAL IONIZATION MASS-SPECTROMETRY OF SOME STEROIDS [J].
MILKOVA, TS ;
MOLLOVA, NN ;
POPOV, SS .
BIOLOGICAL MASS SPECTROMETRY, 1991, 20 (10) :636-640
[8]   MINOR AND TRACE STEROLS IN MARINE-INVERTEBRATES .1. GENERAL METHODS OF ANALYSIS [J].
POPOV, S ;
CARLSON, RMK ;
WEGMANN, A ;
DJERASSI, C .
STEROIDS, 1976, 28 (05) :699-732
[9]  
SCHEIKH Y, 1974, TETRAHEDRON, V30, P40955
[10]  
SEREBRYA.EP, 1970, TETRAHEDRON, V26, P5215
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