Photosensitive n-In2O3 / p-InSe Heterojunctions with Nanostructured Surface of the Frontal Layer

被引:0
|
作者
Kovalyuk, Z. D. [1 ]
Katerynchuk, V. M. [1 ]
Kudrynskyi, Z. R. [1 ]
Lytvyn, O. S. [2 ]
机构
[1] Natl Acad Sci Ukraine, Frantsevich Inst Problems Mat Sci, Chernivtsi Dept, 5 Iryny Vilde Str, UA-58001 Chernovtsy, Ukraine
[2] Natl Acad Sci Ukraine, Lashkaryov Inst Semicond Phys, 41 Nauki Pr, UA-03028 Kiev, Ukraine
关键词
Heterojunctions; Layered crystals; Nanostructures; Atomic force microscopy; Oxide films;
D O I
暂无
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We report on photosensitive n-In2O3 / p-InSe heterojunctions with nanostructured In2O3 frontal layer. It was established that photoresponse spectra of the heterojunctions significantly depend on the surface topology of the oxide. this means that the oxide with semiconductor substrate is not only an active component of the structure, but also serves as a cell diffraction material. Surface topology of the oxide was studied by means of the atomic force microscope. At various conditions of oxidation of InSe the surface of the samples contained nanoformations preferably in the form of nanoneedles. Their location has both a disordered and ordered character. A dimensional optical effect in the oxide was revealed due to the anisotropic light absorption in InSe. The higher deviation of incident light from its normal direction due to a nanostructured surface is, the higher variation in the generation of carriers in the semiconductor is. These changes consist in the energy broadening of the heterojunction photoresponse spectrum as well as in the peculiarities of the excitonic line. The higher density and ordering of the nanoneedles on the oxide surface is, the higher long-wave shift and more intensive excitonic peak in the spectrum takes place.
引用
收藏
页数:5
相关论文
共 50 条
  • [31] Molten-salt synthesis of g-C3N4-Cu2O heterojunctions with highly enhanced photocatalytic performance
    Zuo, Shiyu
    Xu, Haiming
    Liao, Wei
    Yuan, Xiangjuan
    Sun, Lei
    Li, Qiang
    Zan, Jie
    Li, Dongya
    Xia, Dongsheng
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2018, 546 : 307 - 315
  • [32] Visible-light-driven aldehyde ammoxidation to nitrile via 'O2-and 'NHx radicals generation over Ni(OH)2/TiO2 p-n heterojunctions
    Zhou, Yiwei
    Zhao, Jian
    Guo, Hairui
    Wang, Cheng
    JOURNAL OF CATALYSIS, 2025, 442
  • [33] Sandwich-Nanostructured NiO-ZnO Nanowires@α-Fe2O3 Film Photoanode with a Synergistic Effect and p-n Junction for Efficient Photoelectrochemical Water Splitting
    Zhang, Chao
    Fan, Weiqiang
    Bai, Hongye
    Yu, Xiaoqiang
    Chen, Chao
    Zhang, Rongxian
    Shi, Weidong
    CHEMELECTROCHEM, 2014, 1 (12): : 2089 - 2097
  • [34] An in situ-fabricated p-Co3O4@n-ZnO surface heterojunction photocatalyst for solar-to-fuel conversion of CO2
    Wang, Qiuyan
    Chen, Kui
    Wang, Shuhui
    Jiang, Daheng
    Ma, Changqiu
    Zhu, Lixin
    Xu, Xiaoliang
    MATERIALS CHEMISTRY FRONTIERS, 2023, 7 (03) : 523 - 534
  • [35] Carbon and silica interlayer influence for the photocatalytic performances of spindle-like α-Fe2O3/Bi2O3 p-n heterostructures
    Sun, Lingling
    Wu, Wei
    Tian, Qingyong
    Lei, Mei
    Dai, Zhigao
    Xiao, Xiangheng
    Ren, Feng
    Jiang, Changzhong
    MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2016, 41 : 411 - 419
  • [36] Templated synthesis of CuCo2O4-modified g-C3N4 heterojunctions for enhanced photoreduction of Hg2+ under visible light
    Alshaikh, Hind
    Shawky, Ahmed
    Roselin, L. Selva
    JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2022, 132
  • [37] Tuning the optoelectronic properties of two-dimensional β-Ga2O3 using surface passivation and the layer thickness
    Wang, Xueting
    Liu, Defeng
    Wang, Xiaowei
    Liu, Zhun
    Luo, Shulin
    COMPUTATIONAL MATERIALS SCIENCE, 2025, 246
  • [38] Creation of Cu2O@TiO2 Composite Photocatalysts with p-n Heterojunctions Formed on Exposed Cu2O Facets, Their Energy Band Alignment Study, and Their Enhanced Photocatalytic Activity under Illumination with Visible Light
    Liu, Lingmei
    Yang, Weiyi
    Sun, Wuzhu
    Li, Qi
    Shang, Jian Ku
    ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (03) : 1465 - 1476
  • [39] Magnetic field enhanced photoreduction of Cr (VI) over the p-n-p BiFeO3/ CoFe2O4/Co3O4 nanocomposites
    Dhanalakshmi, Radhalayam
    Denardin, Juliano C.
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2022, 562
  • [40] Gas Sensing Properties of p-Co3O4/n-TiO2 Nanotube Heterostructures
    Alev, Onur
    Kilic, Alp
    Cakirlar, Cigdem
    Buyukkose, Serkan
    Orturk, Zafer Ziya
    SENSORS, 2018, 18 (04)