FORMATION AND SOLID-STATE STRUCTURE OF A TETRANUCLEAR OXOARYLOXIDE CLUSTER OF BARIUM, [BA4(MU-4-O)(MU-2-OC6H2(CH2NME2)3-2,4,6)6].3(TOLUENE)

被引：42

作者：

TESH, KF ^{[1
]}

HANUSA, TP ^{[1
]}

机构：

[1] VANDERBILT UNIV,DEPT CHEM,NASHVILLE,TN 37235

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 13期

关键词：

D O I：

10.1039/c39910000879

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tetranuclear oxo-aryloxide cluster, [Ba4(mu-4-O)(mu-2-OC6H2(CH2NMe2)3-2,4,6)6].3(toluene), synthesized from the reaction of K[OC6H2(CH2NMe2)3-2,4,6] and Bal2 in tetrahydrofuran, crystallizes from toluene as a tetrahedron of barium atoms encapsulating a single oxo ligand, the metal centres coordinated by six-mu-2-aryloxide groups and the nitrogen atoms of the ortho-dimethylaminomethyl groups.

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页码：879 / 881

页数：3

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