A theory of melting of molecular crystals .3. The liquid crystalline phase

被引:8
|
作者
Ozgan, S
Keskin, M
机构
[1] GAZIOSMANPASA UNIV,FIZ BOLUMU,TOKAT 60110,TURKEY
[2] ERCIYES UNIV,FIZ BOLUMU,KAYSERI 38039,TURKEY
来源
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1995年 / 270卷
关键词
modified Pople and Karasz theory; liquid crystals; solid-nematic and nematic-isotropic liquid transitions;
D O I
10.1080/10587259508031024
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The Pople and Karasz theory of melting of molecular crystals was modified using the third repulsive energy parameter in our previous paper. The new modified model is applied to study thermodynamics of solid-nematic and nematic-isotropic liquid transitions. The thermodynamic properties are evaluated by the Bragg-Williams approximation. The results are compared with the predictions of the original Pople and Karasz theory and its volume dependence modification, as well as some experimental data.
引用
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页码:147 / 157
页数:11
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