GaAs microcrystals were grown by the combination of Ga droplet formation and successive As supply with low-pressure metalorganic chemical vapor deposition. The Ga droplets were formed by Ga(CH3)(3) supply, and they were transformed to GaAs microcrystals by successive AsH3 supply. The size and the density of the GaAs microcrystals were controlled by the deposition conditions of the Ga droplets. Several photoluminescence peaks with high intensities were observed from the GaAs microcrystals sandwiched with AlGaAs layers.