SELECTIVE HYDROGENATION OF CINNAMALDEHYDE OVER RU-SN CATALYSTS

被引：57
作者：
GALVAGNO, S
DONATO, A
NERI, G
PIETROPAOLO, R
CAPANNELLI, G
机构：
[1] UNIV REGGIO CALABRIA,FAC INGN,I-89100 REGGIO CALABRIA,ITALY
[2] UNIV GENOA,DIPARTIMENTO CHIM IND,I-16126 GENOA,ITALY
来源：
JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 78卷 / 02期
关键词：
D O I：
10.1016/0304-5102(93)85041-Q
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Hydrogenation of cinnamaldehyde has been investigated over a series of Ru-Sn/C catalysts having various Sn/Ru ratios. Addition of tin to Ru/C decreases the CO chemisorption capability of the catalyst. The overall turnover frequency of cinnamaldehyde disappearance and the selectivity to cinnamyl alcohol increase with the Sn/Ru ratio. It is suggested that hydrogenation of the -C = O group occurs on sites associated with tin ions. On these sites the carbonyl group is polarized, facilitating hydrogen transfer from an adjacent Ru-H site.
引用
收藏
页码：227 / 236
页数：10
相关论文
共 25 条
[1]  
Agnelli M., 1989, CATAL TODAY, V6, P63
[2]  
[Anonymous], 1979, CATALYTIC HYDROGENAT
[3]   GEOMETRIC AND ELECTRONIC EFFECTS IN THE SELECTIVE HYDROGENATION OF ALPHA,BETA-UNSATURATED ALDEHYDES OVER ZEOLITE-SUPPORTED METALS [J].
BLACKMOND, DG ;
OUKACI, R ;
BLANC, B ;
GALLEZOT, P .
JOURNAL OF CATALYSIS, 1991, 131 (02) :401-411
[4]   X-RAY-SCATTERING STRUCTURAL INVESTIGATION OF PT AND PT-SN CATALYSTS SUPPORTED ON NYLON [J].
COCCO, G ;
ENZO, S ;
GALVAGNO, S ;
POLTARZEWSKI, Z ;
PIETROPAOLO, R .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1985, 81 :321-333
[5]   SURFACE-REACTIONS OF ALKANES AND ORGANOMETALLIC CHEMISTRY APPLIED TO THE STUDY OF PURE AND BIMETALLIC CATALYSTS [J].
COQ, B ;
BITTAR, A ;
TAZI, T ;
FIGUERAS, F .
JOURNAL OF MOLECULAR CATALYSIS, 1989, 55 (1-3) :34-42
[6]   STUDIES ON RUTHENIUM TIN BORIDE CATALYSTS .1. CHARACTERIZATION [J].
DESHPANDE, VM ;
PATTERSON, WR ;
NARASIMHAN, CS .
JOURNAL OF CATALYSIS, 1990, 121 (01) :165-173
[7]   STUDIES ON RUTHENIUM TIN BORIDE CATALYSTS .2. HYDROGENATION OF FATTY-ACID ESTERS TO FATTY ALCOHOLS [J].
DESHPANDE, VM ;
RAMNARAYAN, K ;
NARASIMHAN, CS .
JOURNAL OF CATALYSIS, 1990, 121 (01) :174-182
[8]  
DIDILLON B, 1991, HETEROGENEOUS CATALY, V2, P137
[9]   SELECTIVE HYDROGENATION OF ALPHA, BETA-UNSATURATED ALDEHYDES TO GIVE UNSATURATED ALCOHOLS OVER PLATINUM GERMANIUM CATALYSTS [J].
GALVAGNO, S ;
POLTARZEWSKI, Z ;
DONATO, A ;
NERI, G ;
PIETROPAOLO, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (23) :1729-1731
[10]   HYDROGENATION OF C=C AND C=O GROUPS ON RUTHENIUM-TIN CATALYSTS [J].
GALVAGNO, S ;
DONATO, A ;
NERI, G ;
PIETROPAOLO, R .
CATALYSIS LETTERS, 1991, 8 (01) :9-14
123