THE MISCIBILITY AND PHASE-SEPARATION IN BINARY BLENDS OF POLY(ETHYL METHACRYLATE) WITH STYRENE ACRYLONITRILE COPOLYMERS

被引：14

作者：

LATH, D

COWIE, JMG

LATHOVA, E

机构：

[1] SLOVAK ACAD SCI,INST POLYMER,CS-84236 BRATISLAVA,CZECHOSLOVAKIA

[2] HERIOT WATT UNIV,DEPT CHEM,EDINBURGH EH14 4AS,MIDLOTHIAN,SCOTLAND

来源：

POLYMER BULLETIN | 1992年 / 28卷 / 03期

关键词：

D O I：

10.1007/BF00294836

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The miscibility and lower critical solution behaviour of pol(ethyl methacrylate) with poly(styrene-stat-acrylonitrile) have been studied. Poly(ethyl methacrylate) is miscible with styrene/acrylonitrile copolymers having acrylonitrile contents between 9 and 34 wt %. By increasing the size of the pendant group from methyl to ethyl, the repulsive interaction between the methacrylate and acrylonitrile increases, but that between the methacrylate and styrene decreases.

引用

收藏

页码：361 / 366

页数：6

相关论文

共 27 条

[1] MISCIBILITY OF POLY(ACRYLONITRILE-CO-STYRENE) WITH POLY[STYRENE-CO-(MALEIC ANHYDRIDE)] AND POLY[STYRENE-CO-(N-PHENYLMALEIMIDE)] [J].

AOKI, Y .

MACROMOLECULES, 1988, 21 (05) :1277-1282

[2]

BARTON J, 1977, CHEM ZVESTI, V31, P265

[3]

Chiou J. S., 1982, Polymer, V23, P1543, DOI 10.1016/0032-3861(82)90259-2

[4] MISCIBILITY MAPPING IN SOME BLENDS INVOLVING POLY(STYRENE-CO-ACRYLONITRILE) [J].

COWIE, JMG ;

LATH, D .

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1988, 16 :103-112

[5] PREDICTION OF THE MISCIBILITY RANGE IN BLENDS OF POLY(STYRENE-CO-ACRYLONITRILE) AND POLY(N-PHENYL ITACONIMIDE-CO-METHYL METHACRYLATE) - A 6-INTERACTION-PARAMETER SYSTEM [J].

COWIE, JMG ;

REID, VMC ;

MCEWEN, IJ .

POLYMER, 1990, 31 (03) :486-489

[6]

COWIE JMG, 1990, POLYMER, V31, P906

[7] EFFECT OF COPOLYMER COMPOSITION ON THE MISCIBILITY OF BLENDS OF STYRENE ACRYLONITRILE COPOLYMERS WITH POLY(METHYL METHACRYLATE) [J].

FOWLER, ME ;

BARLOW, JW ;

PAUL, DR .

POLYMER, 1987, 28 (07) :1177-1184

[8] MISCIBLE BLENDS OF POLY(STYRENE-CO-ACRYLONITRILE) AND POLY(ALPHA-METHYL STYRENE-CO-ACRYLONITRILE) WITH HYDROXYL-CONTAINING POLYMETHACRYLATES [J].

GOH, SH ;

SIOW, KS .

JOURNAL OF APPLIED POLYMER SCIENCE, 1986, 32 (02) :3407-3412

[9] MISCIBLE BLENDS OF POLY(STYRENE-CO-ACRYLONITRILE) AND POLY(ALPHA-METHYL STYRENE-CO-ACRYLONITRILE) WITH POLY(METHYL METHACRYLATE) CONTAINING STERICALLY HINDERED AMINE GROUP [J].

GOH, SH ;

LEE, SY ;

SIOW, KS .

JOURNAL OF APPLIED POLYMER SCIENCE, 1986, 31 (07) :2055-2060

[10] MISCIBILITY OF POLY(STYRENE-CO-ACRYLONITRILE) AND POLY(ALPHA-METHYL STYRENE-CO-ACRYLONITRILE) WITH COPOLYMERS OF METHYL-METHACRYLATE [J].

GOH, SH ;

SIOW, KS .

JOURNAL OF APPLIED POLYMER SCIENCE, 1984, 29 (01) :99-103