PROTON TRANSPORT IN THE CATALYZED GAS-PHASE ISOMERIZATION OF PROTONATED MOLECULES

被引：169

作者：

BOHME, DK ^{[1
]}

机构：

[1] YORK UNIV,CTR RES EARTH & SPACE SCI,N YORK M3J 1P3,ONTARIO,CANADA

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES | 1992年 / 115卷 / 2-3期

关键词：

ION MOLECULE REACTIONS; PROTON TRANSFER; ISOMERIZATION; CATALYSIS;

D O I：

10.1016/0168-1176(92)85035-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Recent theoretical and experimental results for selected ions and ion/molecule reactions are examined which provide insight into fundamental aspects of the isomerization of protonated heteronuclear molecules. The isomerization is viewed in terms of a "proton transport" mechanism in which a "foreign" molecule transports the proton from a high-energy site to a low-energy site of the protonated molecule and thereby catalyzes the isomerization.

引用

页码：95 / 110

页数：16

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