Acetate adsorbs onto platinum surfaces under moderate conditions and the presence of acetate on the electrode surface is apparent by voltammetric studies. The adsorption of acetate lends an unusual stability to layers of zinc acetate on the electrode surface. The reduction of an oxidized platinum surface under a zinc acetate coating is sensitive to polar organic molecules in the bulk solution. This sensitivity may provide an avenue to a new class of analytical sensors.
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SUNY Albany, Dept Chem, 1400 Washington Ave, Albany, NY 12222 USA
Univ Rostock, Dept Chem, D-18059 Rostock, GermanySUNY Albany, Dept Chem, 1400 Washington Ave, Albany, NY 12222 USA
Biala, Katarzyna
Sedova, Ada
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SUNY Albany, Dept Chem, 1400 Washington Ave, Albany, NY 12222 USASUNY Albany, Dept Chem, 1400 Washington Ave, Albany, NY 12222 USA
Sedova, Ada
Flechsig, Gerd-Uwe
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SUNY Albany, Dept Chem, 1400 Washington Ave, Albany, NY 12222 USA
Univ Rostock, Dept Chem, D-18059 Rostock, Germany
Gensor GmbH, D-18057 Rostock, GermanySUNY Albany, Dept Chem, 1400 Washington Ave, Albany, NY 12222 USA