ACETATE ADSORPTION AND METAL OVERLAYERS ON ELECTRODE SURFACES

被引：5
|
作者：
ROOT, DP
PRIYANTHA, N
机构：
[1] UNIV HAWAII,DEPT CHEM,DIV NAT SCI,HILO,HI 96720
[2] BREWER ENVIRONM SERV,PAPAIKOU,HI 96781
来源：
ELECTROCHIMICA ACTA | 1991年 / 36卷 / 14期
关键词：
MODIFIED ELECTRODES; ELECTROCHEMICAL SENSORS; ACETATE ADSORPTION; PLATINUM ELECTRODES; VOLTAMMETRY;
D O I：
10.1016/0013-4686(91)85217-U
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Acetate adsorbs onto platinum surfaces under moderate conditions and the presence of acetate on the electrode surface is apparent by voltammetric studies. The adsorption of acetate lends an unusual stability to layers of zinc acetate on the electrode surface. The reduction of an oxidized platinum surface under a zinc acetate coating is sensitive to polar organic molecules in the bulk solution. This sensitivity may provide an avenue to a new class of analytical sensors.
引用
收藏
页码：2109 / 2112
页数：4
相关论文
共 50 条
  • [1] pH effect on acetate adsorption at Pt(111) electrode
    Zuo, Xia Qing
    Chen, Wei
    Yu, Anni
    Xu, Mian Le
    Cai, Jun
    Chen, Yan-Xia
    ELECTROCHEMISTRY COMMUNICATIONS, 2018, 89 : 6 - 9
  • [2] The adsorption of ethene on vicinally stepped electrode surfaces and the effect of temperature
    Loeffler, Th.
    Bussar, R.
    Xiao, X.
    Ernst, S.
    Baltruschat, H.
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2009, 629 (1-2) : 1 - 14
  • [3] Determination of Isotherm for Acetate and Formate Adsorption at Pt(111) Electrode by Fast Scan Voltammetry
    Xu, Jie
    Lin, Chu-hong
    Mei, Dong
    Zhang, Zun-biao
    Yuan, Dao-fu
    Chen, Yan-xia
    CHINESE JOURNAL OF CHEMICAL PHYSICS, 2013, 26 (02) : 191 - 197
  • [4] Thermodynamic studies of phosphate adsorption on Pt(111) electrode surfaces in perchloric acid solutions
    Mostany, Jorge
    Martinez, Pedro
    Climent, Victor
    Herrero, Enrique
    Feliu, Juan M.
    ELECTROCHIMICA ACTA, 2009, 54 (24) : 5836 - 5843
  • [5] Decorated Electrode Surfaces with Nanostructures and Metal-Organic Frameworks as Transducers for Sensing
    Caruncho-Perez, Sara
    Diez, Aida M.
    Prado-Comesana, Ana
    Pazos, Marta
    Sanroman, Maria Angeles
    Gonzalez-Romero, Elisa
    SENSORS, 2024, 24 (20)
  • [6] Modelling of cyclic voltammograms for two-step metal deposition on an inert electrode with adsorption
    S. Martinet
    J. Bouteillon
    J. P. Caire
    Journal of Applied Electrochemistry, 1998, 28 : 819 - 825
  • [7] Modelling of cyclic voltammograms for two-step metal deposition on an inert electrode with adsorption
    Martinet, S
    Bouteillon, J
    Caire, JP
    JOURNAL OF APPLIED ELECTROCHEMISTRY, 1998, 28 (08) : 819 - 825
  • [8] Adsorption Kinetics and Thermodynamics of Hydroquinone onto a Polycrystalline Gold Electrode
    Naito, Kumi
    Iezaki, Hirokazu
    Yasui, Takashi
    Takada, Kazutake
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2018, 165 (09) : H455 - H459
  • [9] Adsorption of Hydroquinone to Polycrystalline Gold Electrode and Its Effect on the Electrochemical Properties
    Naito, Kumi
    Maeda, Yuri
    Yasui, Takashi
    Takada, Kazutake
    Yuchi, Akio
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2017, 164 (09) : H670 - H674
  • [10] How Reactive are Metal Surfaces in Solution? A Comparison of the Electrochemical Adsorption of Organic Molecules on Pt At Low Potentials
    Gomes, Janaina F.
    Bergamaski, Kleber
    Miranda, Paulo B.
    ELECTROCATALYSIS, 2014, 5 (01) : 1 - 4
12345