LIQUID-LIQUID PHASE-EQUILIBRIA OF AQUEOUS 2-PHASE SYSTEMS CONTAINING SALTS AND POLYETHYLENE-GLYCOL

被引：72
作者：
VOROS, N
PROUST, P
FREDENSLUND, A
机构：
[1] TECH UNIV DENMARK, ENGN RES CTR IVC SEP, INST KEMITEKNIK, DK-2800 LYNGBY, DENMARK
[2] PONTIFICIA UNIV CATOLICA VALPARAISO, VALPARAISO, CHILE
来源：
FLUID PHASE EQUILIBRIA | 1993年 / 90卷 / 02期
关键词：
EXPERIMENTS; DATA; LIQUID LIQUID EQUILIBRIA; AQUEOUS SOLUTIONS; SALTS; POLYETHYLENE GLYCOL;
D O I：
10.1016/0378-3812(93)85071-S
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Liquid-liquid phase equilibria of the ternary systems: (a) polyethylene glycol -ammonium sulfate - water and (b) polyethylene glycol - sodium carbonate -water have been determined experimentally at 15-degrees, 25-degrees, 35-degrees and 45-degrees-C and for two, different molecular weights of the polymer (Avg. M.W. 1000 and 2000). Details of the glass cell and of the equilibration and analytical procedures used are described. Equilibrium data along with phase diagrams are presented. Finally the effect of temperature and of the molecular weight of the polymer are also discussed.
引用
收藏
页码：333 / 353
页数：21
相关论文
共 50 条
  • [31] Mixing enthalpy and liquid-liquid equilibrium of aqueous polyethylene glycol (PEG) solutions
    Dorn, U.
    Enders, S.
    MOLECULAR PHYSICS, 2014, 112 (17) : 2310 - 2324
  • [32] Liquid-liquid distribution of B group vitamins in polyethylene glycol-based systems
    Ya. I. Korenman
    A. V. Zykov
    N. Ya. Mokshina
    Russian Journal of Physical Chemistry A, 2011, 85
  • [33] Liquid-liquid distribution of B group vitamins in polyethylene glycol-based systems
    Korenman, Ya. I.
    Zykov, A. V.
    Mokshina, N. Ya.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 85 (05) : 862 - 865
  • [34] Liquid-liquid phase equilibria for ternary systems of several polyethers with NaCl and H2O
    Milosevic, Miran
    Staal, Koen J. J.
    Schuur, Boelo
    de Haan, Andre B.
    FLUID PHASE EQUILIBRIA, 2014, 376 : 76 - 84
  • [35] Liquid-liquid equilibria in aqueous two-phase ethanol/salt systems at different temperatures and their application to anthocyanins extraction
    Rocha Caldeira, Ana Clara
    Filho Lopes de Franca, Wanderley
    Converti, Attilio
    Nogueira Lima, William James
    Sampaio, Fabio Coelho
    de Faria, Janaina Teles
    FOOD SCIENCE AND TECHNOLOGY, 2019, 39 : 711 - 717
  • [36] KINETICS OF PHASE-SEPARATION FOR POLYETHYLENE GLYCOL-PHOSPHATE 2-PHASE SYSTEMS
    KAUL, A
    PEREIRA, RAM
    ASENJO, JA
    MERCHUK, JC
    BIOTECHNOLOGY AND BIOENGINEERING, 1995, 48 (03) : 246 - 256
  • [37] Influence of the Salting-Out Ability and Temperature on the Liquid-Liquid Equilibria of Aqueous Two-Phase Systems Based on Ionic Liquid-Organic Salts-Water
    Li, Yuliang
    Lu, Xiaojia
    He, Wenting
    Huang, Rong
    Zhao, Yingjie
    Wang, Zhigiang
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2016, 61 (01) : 475 - 486
  • [38] Liquid-liquid extraction of molybdenum(VI) using aqueous two-phase systems (ATPS) consisting of polyethylene glycol (PEG) and sodium, ammonium and copper(II) salts: Comparison with conventional solvent extraction
    Martinez, Monserrat
    Barrueto, Yahaira
    Jimenez, Yecid P.
    HYDROMETALLURGY, 2023, 219
  • [39] Experimental liquid-liquid phase equilibria for binary systems: ethanenitrile with several hydrocarbon isomers
    Eustaquio-Rincon, R
    Ramirez, LF
    Trejo, A
    FLUID PHASE EQUILIBRIA, 1998, 149 (1-2) : 177 - 189
  • [40] Applications of ionic liquids in biphasic separation: Aqueous biphasic systems and liquid-liquid equilibria
    Shukla, Shashi Kant
    Pandey, Shubha
    Pandey, Siddharth
    JOURNAL OF CHROMATOGRAPHY A, 2018, 1559 : 44 - 61
12345