THE BENZOSTABASE PROTECTING GROUP FOR PRIMARY AMINES - APPLICATION TO AROMATIC-AMINES

被引：24

作者：

BONARLAW, RP ^{[1
]}

DAVIS, AP ^{[1
]}

DORGAN, BJ ^{[1
]}

机构：

[1] UNIV DUBLIN TRINITY COLL,DEPT CHEM,DUBLIN 2,IRELAND

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 46期

关键词：

D O I：

10.1016/S0040-4039(00)97157-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Anilines can be protected as "benzostabase" (BSB) derivatives by dehydrogenative silylation with 1,2-bis(dimethylsilyl)benzene. The derivatives have useful acid stability and are stable to chromatography on silica gel. It is demonstrated that the BSB group can be carried through a number of C-C bond-forming reactions. © 1990.

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页码：6721 / 6724

页数：4

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