LANTHANOID COMPLEXES WITH HEXAMETHYLPHOSPHORAMIDE (HMPA) LIGAND - PREPARATION AND CRYSTAL-STRUCTURE OF YTTERBIUM COMPLEXES OF HMPA, [YB(H2O)5(HMPA)2]CL3.H2O.HMPA AND YBCL3(HMPA)3

被引：44
作者：
HOU, ZM
KOBAYASHI, K
YAMAZAKI, H
机构：
来源：
CHEMISTRY LETTERS | 1991年 / 02期
关键词：
D O I：
10.1246/cl.1991.265
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of YbCl3 with hexamethylphosphoramide (HMPA) in THF under air gave [Yb(H2O)5(HMPA)2]Cl3.H2O.HMPA and YbCl3(HMPA)3 respectively, depending on the recrystallization conditions. Both complexes have been structurally characterized by X-ray crystallography.
引用
收藏
页码：265 / 268
页数：4
相关论文
共 32 条
[1]  
AMIRKHANOV VM, 1986, UKR KHIM ZH+, V52, P1240
[2]   CRYSTAL-STRUCTURES OF (PH2C=NLI-NC5H5)4 AND [CILI-O=P(NME2)3]4 - DISCRETE TETRAMERIC PSEUDO-CUBANE CLUSTERS WITH BRIDGING OF LI3 TRIANGLES BY NITROGEN AND BY CHLORINE ATOMS [J].
BARR, D ;
CLEGG, W ;
MULVEY, RE ;
SNAITH, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (02) :79-80
[3]   2 MONOMERIC, OCTAHEDRAL COMPLEXES OF ALKALINE-EARTH METAL-SALTS - SYNTHESES, PHYSICAL CHARACTERISTICS, AND CRYSTAL-STRUCTURES OF SRI2.4HMPA AND SR(NCS)2.4HMPA [HMPA=O-P(NME2)3] [J].
BARR, D ;
BROOKER, AT ;
DOYLE, MJ ;
DRAKE, SR ;
RAITHBY, PR ;
SNAITH, R ;
WRIGHT, DS .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (14) :893-895
[4]  
BARR D, 1989, ANGEW CHEM INT EDIT, V29, P285
[5]  
BARR D, 1989, INORG CHEM, V28, P1768
[6]   STRUCTURE DU DINITRATODIOXOBIS(TRIAMIDE "HEXAMETHYLPHOSPHORIQUE)URANIUM(VI), [UO2(NO3)2(C6H18N3OP)2] [J].
CHARPIN, PP ;
LANCE, M ;
SOULIE, E ;
VIGNER, D .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 (JUN) :884-886
[7]   CRYSTAL AND MOLECULAR STRUCTURE OF YTTERBIUM ACETYLACETONATE MONOHYDRATE [J].
CUNNINGHAM, JA ;
SANDS, DE ;
WAGNER, WF ;
RICHARDSON, MF .
INORGANIC CHEMISTRY, 1969, 8 (01) :22-+
[8]  
de Wet J. F., 1971, Inorganic and Nuclear Chemistry Letters, V7, P1041, DOI 10.1016/0020-1650(71)80026-0
[9]   4-CO-ORDINATE AND 5-CO-ORDINATE LANTHANIDE(II) ARYLOXIDES - X-RAY STRUCTURES OF THE BIS(2,6-DI-TERT-BUTYL-4-METHYLPHENOXO)YTTERBIUM(II) COMPLEXES [YB(OAR)2(L)2] AND [YB(OAR)2(L')3] [AR = C6H2BU-TERT-2-2,6-ME-4, L = TETRAHYDROFURAN (THF) OR OET2, L' = THF] [J].
DEACON, GB ;
HITCHCOCK, PB ;
HOLMES, SA ;
LAPPERT, MF ;
MACKINNON, P ;
NEWNHAM, RH .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (14) :935-937
[10]  
DEBOLSTER MW, 1971, RECL TRAV CHIM PAY-B, V90, P477
1234