A SELF-CONSISTENT THEORY OF DRESSED MICELLES

被引：103

作者：

HAYTER, JB

机构：

[1] Solid State Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-8218

来源：

LANGMUIR | 1992年 / 8卷 / 12期

关键词：

D O I：

10.1021/la00048a005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dressed micelle model of Evans, Mitchell, and Ninham is recast in self-consistent form and solved analytically. Consideration of the adsorption excess of ions about the micelle leads to a remarkably simple expression for the degree of micellar ionization. Values calculated from this theory, which has no free parameters, generally agree well with experimental values measured by neutron scattering.

引用

收藏

页码：2873 / 2876

页数：4

相关论文

共 11 条

[1] EFFECT OF SURFACTANT CHARGE ON POLYMER MICELLE INTERACTION - N-DODECYLDIMETHYLAMINE OXIDE [J].

BRACKMAN, JC ;

ENGBERTS, JBFN .

LANGMUIR, 1992, 8 (02) :424-428

[2] EXPERIMENTAL TEST OF A THEORY OF DRESSED MICELLES - THE CASE OF THE MONO-VALENT COUNTERION [J].

CHAO, YS ;

SHEU, EY ;

CHEN, SH .

JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (22) :4862-4866

[3] EFFECT OF INTERFACIAL CHARGE ON MICELLAR STRUCTURE [J].

CHEVALIER, Y ;

BELLONI, L ;

HAYTER, JB ;

ZEMB, T .

JOURNAL DE PHYSIQUE, 1985, 46 (05) :749-759

[4] ION BINDING AND THE HYDROPHOBIC EFFECT [J].

EVANS, DF ;

NINHAM, BW .

JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (24) :5025-5032

[5] ION BINDING AND DRESSED MICELLES [J].

EVANS, DF ;

MITCHELL, DJ ;

NINHAM, BW .

JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (25) :6344-6348

[6] DETERMINATION OF MICELLE STRUCTURE AND CHARGE BY NEUTRON SMALL-ANGLE SCATTERING [J].

HAYTER, JB ;

PENFOLD, J .

COLLOID AND POLYMER SCIENCE, 1983, 261 (12) :1022-1030

[7]

HAYTER JB, 1982, CHEM PHYS LETT, V93, P91, DOI 10.1016/0009-2614(82)85062-8

[8]

HAYTER JB, 1986, ORNL6306 REP, P154

[9]

HUNTER RJ, 1989, F COLLOID SCI, V2, pCH12

[10]

LOEB AL, 1961, ELECTRICAL DOUBLE LA